Electrochemical radical-polar crossover: a radical approach to polar chemistry

Z Tan, H Zhang, K Xu, C Zeng - Science China Chemistry, 2024 - Springer
Radical-polar crossover (RPC) reaction bridges the gap between one-and two-electron
reactivities, thus providing an ideal solution to overcome the limitations of both radical and …

Palladium-Catalyzed Aerobic Oxidative Spirocyclization of Alkyl Amides with Maleimides via β-C(sp3)–H Activation

A Dutta, M Jeganmohan - Organic Letters, 2023 - ACS Publications
An efficient method for the synthesis of bicyclic spirodiamine molecules via β-C (sp3)–H
bond activation of aliphatic amides, followed by cyclization with maleimides, has been …

Cp2Fe-Mediated Electrochemical Synthesis of Phosphorylated Oxindoles and Indolo[2,1-a]isoquinolin-6(5H)-ones

X Zhou, J Wang, Y Shen, D Ma, Y Zhao… - The Journal of Organic …, 2023 - ACS Publications
An efficient and environmentally friendly electrochemical synthesis of phosphorylated
oxindoles and indolo [2, 1-a] isoquinolin-6 (5 H)-ones mediated by readily available Cp2Fe …

Ferrocene as a Redox Catalyst for Organic Electrosynthesis

N Chen, ZJ Wu, HC Xu - Israel Journal of Chemistry, 2024 - Wiley Online Library
Despite substantial advancements in thermal and photochemical catalysis, the evolution of
similar processes within the realm of organic electrochemistry has seen a slower pace …

Selective Synthesis of Mono-and Bis-Phosphorylated (Dihydro) pyrans via TMSCl-Mediated Cascade Phosphorylation Cycloisomerization of Enynones

YF Qiu, Q Wang, JH Cao, DQ Xue, M Li, ZJ Quan… - Organic …, 2024 - ACS Publications
A chlorotrimethylsilane (TMSCl)-mediated cascade phosphorylation and cycloisomerization
of enynones with diphenylphosphine oxides is presented. This methodology enables the …

Scalable diastereoselective electrosynthesis of spiro [benzofuran-2, 2′-furan]-3-ones

I Yavari, S Shaabanzadeh… - The Journal of Organic …, 2023 - ACS Publications
Spirobenzofuran scaffolds, because of their three-dimensional structure, are incorporated
into several valuable natural products and drug candidate molecules. Herein, with the …

Cascade Electrochemical Aerobic Oxygenation of 2-Substituted Indoles and Electrochemical [5+ 3] Annulation with Amidines: Access to Eight-Membered Benzo [1, 3 …

W Zhuang, F Xiao, Y Chen, X Zhang… - The Journal of Organic …, 2024 - ACS Publications
The cascade electrochemical C3-selective aerobic oxygenation of 2-substituted indoles and
electrochemical [5+ 3] annulation with amidines through an undivided cell galvanostatic …

A Multicomponent [2+2+1] Cascade Cyclization to Synthesize Thiazol-2(3H)-one

M Wang, Y Gong, Y Shi, Q Zhao, XJ Zhao… - The Journal of …, 2024 - ACS Publications
A multicomponent [2+ 2+ 1] tandem cyclization of alkynones with amines and water using
potassium thiocyanate as electrolyte and raw material to access thiazol-2 (3 H)-ones has …

Electrochemical synthesis of phosphorylated azaspiro [4.5] di/trienones through dearomative spirocyclization

X Zhou, J Wang, D Ma, Y Shen, Y Zhao… - Chemical …, 2024 - pubs.rsc.org
Cp2Fe-mediated electrochemical synthesis of a diverse array of phosphorylated azaspiro
[4.5] di/trienones has been developed, which demonstrated broad substrate scope and good …

Recent Progress in Metal-Catalyzed C (sp³)-P Bond Formation

JL Tu, Z Shen, B Huang - Tetrahedron, 2024 - Elsevier
The construction of C (sp³)-P bonds is of paramount importance in organic synthesis,
catalysis, and materials science. Organophosphorus compounds containing C (sp³)-P bonds …