Sustainability assessment of mechanochemistry by using the twelve principles of green chemistry

KJ Ardila‐Fierro, JG Hernández - ChemSusChem, 2021 - Wiley Online Library
In recent years, mechanochemistry has been growing into a widely accepted alternative for
chemical synthesis. In addition to their efficiency and practicality, mechanochemical …

The mechanochemical synthesis of polymers

A Krusenbaum, S Grätz, GT Tigineh… - Chemical Society …, 2022 - pubs.rsc.org
Mechanochemistry–the utilization of mechanical forces to induce chemical reactions–is a
rarely considered tool for polymer synthesis. It offers numerous advantages such as reduced …

Advancing mechanochemical synthesis by combining milling with different energy sources

V Martinez, T Stolar, B Karadeniz, I Brekalo… - Nature Reviews …, 2023 - nature.com
Owing to its efficiency and unique reactivity, mechanochemical processing of bulk solids has
developed into a powerful tool for the synthesis and transformation of various classes of …

A guide to direct mechanocatalysis

S Hwang, S Grätz, L Borchardt - Chemical Communications, 2022 - pubs.rsc.org
Direct mechanocatalysis (DM) describes solvent-free catalytic reactions that are initiated by
mechanical forces in mechanochemical reactors such as ball mills. The distinctive feature of …

Tackling solubility issues in organic synthesis: solid-state cross-coupling of insoluble aryl halides

T Seo - Palladium-Catalyzed Mechanochemical Cross …, 2024 - Springer
Conventional organic synthesis generally relies on the use of liquid organic solvents to
dissolve the reactants. Therefore, reactions of sparingly soluble or insoluble substrates are …

Metal-mediated and metal-catalyzed reactions under mechanochemical conditions

A Porcheddu, E Colacino, L De Luca, F Delogu - ACS Catalysis, 2020 - ACS Publications
The extraordinary impact of metal-based complexes on synthetic methods is still recognized
nowadays, and attempts are currently undertaken to further extend the use of metal-assisted …

Mechanochemical cross-coupling reactions

K Kubota, H Ito - Trends in chemistry, 2020 - cell.com
In recent years, solvent-less mechanochemical organic transformations using ball milling
have come to the forefront of organic synthesis as cleaner and sustainable synthetic …

Toward Mechanistic Understanding of Mechanochemical Reactions Using Real-Time In Situ Monitoring

S Lukin, LS Germann, T Friščić… - Accounts of chemical …, 2022 - ACS Publications
Conspectus The past two decades have witnessed a rapid emergence of interest in
mechanochemistry–chemical and materials reactivity achieved or sustained by the action of …

Solid‐State Radical C− H Trifluoromethylation Reactions Using Ball Milling and Piezoelectric Materials

Y Pang, JW Lee, K Kubota, H Ito - … Chemie International Edition, 2020 - Wiley Online Library
The application of piezoelectricity for the generation of trifluoromethyl (CF3) radicals is
reported together with the development of a method for the mechanochemical C− H …

Mechanochemical techniques for the activation and use of zero-valent metals in synthesis

AC Jones, JA Leitch, SE Raby-Buck, DL Browne - Nature Synthesis, 2022 - nature.com
Activating raw, zero-valent metals is an essential capability for chemical processes, which
include synthesis and catalysis. In recent years there has been the discovery and growing …