Synthesis of sulfoximines and sulfonimidamides using hypervalent iodine mediated NH transfer
The development of NH transfer reactions using hypervalent iodine and simple sources of
ammonia has facilitated the synthesis of sulfoximines and sulfonimidamides for applications …
ammonia has facilitated the synthesis of sulfoximines and sulfonimidamides for applications …
Progress in the Enantioselective Synthesis of Sulfur (VI) Compounds
P Zhao, Q Zeng - Chemistry–A European Journal, 2023 - Wiley Online Library
In recent years, there has been a notable surge in the prominence of enantioenriched sulfur
(VI) compounds within the chemical science, particularly in the realm of bioactive molecules …
(VI) compounds within the chemical science, particularly in the realm of bioactive molecules …
One-pot tandem oxidative bromination and amination of sulfenamide for the synthesis of sulfinamidines
G Yang, H Huang, X Nie, S Zhang, X Cui… - The Journal of …, 2023 - ACS Publications
The sulfinamidines as aza analogues of sulfinamides received limited attention from both
organic chemists and pharmaceutical chemists. Herein, we present a tandem …
organic chemists and pharmaceutical chemists. Herein, we present a tandem …
Hypervalent iodine mediated synthesis of sulfinamidines from sulfenamides
G Huang, J Ye, MA Bashir, Y Chen… - The Journal of Organic …, 2023 - ACS Publications
In this study, we present a novel, efficient method for the oxidative amination of sulfenamides
using diacetoxyiodobenzene (PhI (OAc) 2) and amines under basic conditions. This …
using diacetoxyiodobenzene (PhI (OAc) 2) and amines under basic conditions. This …
Ex situ Generation of Thiazyl Trifluoride (NSF3) as a Gaseous SuFEx Hub**
BY Li, K Su, L Van Meervelt, SHL Verhelst… - Angewandte …, 2023 - Wiley Online Library
Abstract Sulfur (VI)‐fluoride exchange (SuFEx) chemistry, an all‐encompassing term for
substitution events that replace fluoride at an electrophilic sulfur (VI), enables the rapid and …
substitution events that replace fluoride at an electrophilic sulfur (VI), enables the rapid and …
Mechanochemical Copper-Catalyzed Synthesis of NH-Sulfonimidamides by Oxidative Amination of Primary Sulfinamides
P Wu, L Ling, Y Hu, S Pan, C Bolm - ACS Sustainable Chemistry …, 2024 - ACS Publications
A mechanochemical copper-catalyzed oxidative amination of primary sulfinamides has been
developed, leading to N H-sulfonimidamides in moderate to good yields under solvent-free …
developed, leading to N H-sulfonimidamides in moderate to good yields under solvent-free …
Aerobic CuBr2-Catalyzed Oxidative Coupling Reaction of Amidines with Exocyclic α,β-Unsaturated Cycloketones for the Synthesis of Spiroimidazolines
FH Huang, MJ Li, ZY He, QY Zhu… - The Journal of …, 2023 - ACS Publications
A CuBr2-catalyzed cascade reaction of amidines with exocyclic α, β-unsaturated
cycloketones was developed, affording a large variety of spiroimidazolines in moderate to …
cycloketones was developed, affording a large variety of spiroimidazolines in moderate to …
A Sulfur Monoxide Surrogate Designed for the Synthesis of Sulfoxides and Sulfinamides
D Austrup, F Saito - Angewandte Chemie, 2023 - Wiley Online Library
Sulfur monoxide (SO) is a highly reactive species that cannot be isolated in bulk. However,
SO can play a pivotal role as a fundamental building block in organic synthesis. Reported …
SO can play a pivotal role as a fundamental building block in organic synthesis. Reported …
The Catalytic Synthesis of Aza-Sulfur Functional Groups
MK Wei, MC Willis - Synthesis, 2024 - thieme-connect.com
Sulfur-containing compounds are found in myriad applications. Sulfones and sulfonamides
are the most common functional groups used in medicinal and agrochemical endeavours …
are the most common functional groups used in medicinal and agrochemical endeavours …
Synthesis of Sulfonimidamide‐Based 1, 2‐Benzothiazines by [4+ 2] Oxidative Annulation of Sulfonimidamides and Alkynes in Water under Visible Light
K Natarajan, S Ravindra… - European Journal of …, 2024 - Wiley Online Library
Herein, we disclose a visible‐light‐induced rhodium‐catalyzed oxidative C− H/N− H bond
activation of sulfonimidamides (SIAs) and subsequent [4+ 2] annulation with an alkyne in …
activation of sulfonimidamides (SIAs) and subsequent [4+ 2] annulation with an alkyne in …