Electrochemical late-stage functionalization

Y Wang, S Dana, H Long, Y Xu, Y Li… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …

Recent advances in n-type and ambipolar organic semiconductors and their multi-functional applications

Y Zhang, Y Wang, C Gao, Z Ni, X Zhang… - Chemical Society …, 2023 - pubs.rsc.org
Organic semiconductors have received broad attention and research interest due to their
unique integration of semiconducting properties with structural tunability, intrinsic flexibiltiy …

Bayesian reaction optimization as a tool for chemical synthesis

BJ Shields, J Stevens, J Li, M Parasram, F Damani… - Nature, 2021 - nature.com
Reaction optimization is fundamental to synthetic chemistry, from optimizing the yield of
industrial processes to selecting conditions for the preparation of medicinal candidates …

Photoredox-catalyzed C–H functionalization reactions

N Holmberg-Douglas, DA Nicewicz - Chemical reviews, 2021 - ACS Publications
The fields of C–H functionalization and photoredox catalysis have garnered enormous
interest and utility in the past several decades. Many different scientific disciplines have …

N-Heterocyclic carbene complexes in C–H activation reactions

Q Zhao, G Meng, SP Nolan, M Szostak - Chemical reviews, 2020 - ACS Publications
In this contribution, we provide a comprehensive overview of C–H activation methods
promoted by NHC–transition metal complexes, covering the literature since 2002 (the year …

Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts

S Rana, JP Biswas, S Paul, A Paik… - Chemical Society Reviews, 2021 - pubs.rsc.org
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

Organothianthrenium salts: synthesis and utilization

H Meng, MS Liu, W Shu - Chemical Science, 2022 - pubs.rsc.org
Organothianthrenium salts are a class of compounds containing a positively charged sulfur
atom and a neutral sulfur atom. Over the past years, organothianthrenium salts have been …

Transition-metal catalyzed C–H activation as a means of synthesizing complex natural products

SK Sinha, P Ghosh, S Jain, S Maiti… - Chemical Society …, 2023 - pubs.rsc.org
Over the past few decades, the advent of C–H activation has led to a rethink among
chemists about the synthetic strategies employed for multi-step transformations. Indeed …

The continuum of carbon–hydrogen (C–H) activation mechanisms and terminology

KM Altus, JA Love - Communications Chemistry, 2021 - nature.com
As a rapidly growing field across all areas of chemistry, CH activation/functionalisation is
being used to access a wide range of important molecular targets. Of particular interest is the …

A decade of electrochemical dehydrogenative C, C-coupling of aryls

JL Röckl, D Pollok, R Franke… - Accounts of Chemical …, 2019 - ACS Publications
Conspectus The importance of sustainable and green synthetic protocols for the synthesis of
fine chemicals has rapidly increased during the last decades in an effort to reduce the use of …