Nickel and iron pincer complexes as catalysts for the reduction of carbonyl compounds
Conspectus The reductions of aldehydes, ketones, and esters to alcohols are important
processes for the synthesis of chemicals that are vital to our daily life, and the reduction of …
processes for the synthesis of chemicals that are vital to our daily life, and the reduction of …
Nickel hydride complexes
NA Eberhardt, H Guan - Chemical reviews, 2016 - ACS Publications
Nickel hydride complexes, defined herein as any molecules bearing a nickel hydrogen
bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are …
bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are …
Pincer ligands—Tunable, versatile and applicable
Pincer ligands continue to generate interest owing to the unusual properties they impart on
metal centers and consequently on the complexes they are involved in. These ligands and …
metal centers and consequently on the complexes they are involved in. These ligands and …
Chemoselective alkene hydrosilylation catalyzed by nickel pincer complexes
I Buslov, J Becouse, S Mazza… - Angewandte Chemie …, 2015 - Wiley Online Library
Chemoselective hydrosilylation of functionalized alkenes is difficult to achieve using base‐
metal catalysts. Reported herein is that well‐defined bis (amino) amide nickel pincer …
metal catalysts. Reported herein is that well‐defined bis (amino) amide nickel pincer …
An efficient nickel catalyst for the reduction of carbon dioxide with a borane
S Chakraborty, J Zhang, JA Krause… - Journal of the American …, 2010 - ACS Publications
Nickel hydride with a diphosphinite-based ligand catalyzes the highly efficient reduction of
CO2 with catecholborane, and the hydrolysis of the resulting methoxyboryl species …
CO2 with catecholborane, and the hydrolysis of the resulting methoxyboryl species …
Nickel N-Heterocyclic Carbene-Catalyzed C–Heteroatom Bond Formation, Reduction, and Oxidation: Reactions and Mechanistic Aspects
The chemistry of nickel N-heterocyclic carbene species has blossomed at the beginning of
this century with a particularly rapid acceleration in the last 5 years, as indicated by the fact …
this century with a particularly rapid acceleration in the last 5 years, as indicated by the fact …
Boryl–metal bonds facilitate cobalt/nickel-catalyzed olefin hydrogenation
New approaches toward the generation of late first-row metal catalysts that efficiently
facilitate two-electron reductive transformations (eg, hydrogenation) more typical of noble …
facilitate two-electron reductive transformations (eg, hydrogenation) more typical of noble …
Magnesium-catalysed hydroboration of aldehydes and ketones
M Arrowsmith, TJ Hadlington, MS Hill… - Chemical …, 2012 - pubs.rsc.org
Magnesium-catalysed hydroboration of aldehydes and ketones - Chemical Communications
(RSC Publishing) DOI:10.1039/C2CC30565H Royal Society of Chemistry View PDF …
(RSC Publishing) DOI:10.1039/C2CC30565H Royal Society of Chemistry View PDF …
Non-precious metal complexes with an anionic PCP pincer architecture
S Murugesan, K Kirchner - Dalton Transactions, 2016 - pubs.rsc.org
This perspective article provides an overview of the advancements in the field of non-
precious metal complexes featuring anionic PCP pincer ligands with the inclusion of …
precious metal complexes featuring anionic PCP pincer ligands with the inclusion of …
Reversible substrate activation and catalysis at an intact metal–metal bond using a redox-active supporting ligand
TJ Steiman, C Uyeda - Journal of the American Chemical Society, 2015 - ACS Publications
An electron rich Ni (I)–Ni (I) bond supported by a doubly reduced naphthyridine–diimine
(NDI) ligand reacts rapidly and reversibly with Ph2SiH2 and Et2SiH2 to form stable adducts …
(NDI) ligand reacts rapidly and reversibly with Ph2SiH2 and Et2SiH2 to form stable adducts …