Conspectus The reductions of aldehydes, ketones, and esters to alcohols are important
processes for the synthesis of chemicals that are vital to our daily life, and the reduction of …

Nickel hydride complexes, defined herein as any molecules bearing a nickel hydrogen
bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are …

Pincer ligands continue to generate interest owing to the unusual properties they impart on
metal centers and consequently on the complexes they are involved in. These ligands and …

Chemoselective hydrosilylation of functionalized alkenes is difficult to achieve using base‐
metal catalysts. Reported herein is that well‐defined bis (amino) amide nickel pincer …

Nickel hydride with a diphosphinite-based ligand catalyzes the highly efficient reduction of
CO2 with catecholborane, and the hydrolysis of the resulting methoxyboryl species …

The chemistry of nickel N-heterocyclic carbene species has blossomed at the beginning of
this century with a particularly rapid acceleration in the last 5 years, as indicated by the fact …

New approaches toward the generation of late first-row metal catalysts that efficiently
facilitate two-electron reductive transformations (eg, hydrogenation) more typical of noble …

Magnesium-catalysed hydroboration of aldehydes and ketones - Chemical Communications
(RSC Publishing) DOI:10.1039/C2CC30565H Royal Society of Chemistry View PDF …

This perspective article provides an overview of the advancements in the field of non-
precious metal complexes featuring anionic PCP pincer ligands with the inclusion of …

An electron rich Ni (I)–Ni (I) bond supported by a doubly reduced naphthyridine–diimine
(NDI) ligand reacts rapidly and reversibly with Ph2SiH2 and Et2SiH2 to form stable adducts …