Sustainable protocols for direct C–H bond arylation of (hetero) arenes

G Albano, A Punzi, MAM Capozzi, GM Farinola - Green Chemistry, 2022 - pubs.rsc.org
Direct C–H bond arylation of (hetero) arenes is a very convenient approach for the synthesis
of a wide variety of molecular targets, including compounds of pharmaceutical interest and π …

Asymmetric C–H bond functionalization of ferrocenes: new opportunities and challenges

CX Liu, Q Gu, SL You - Trends in Chemistry, 2020 - cell.com
Ferrocene is of great significance in the fields of organic synthesis, materials science, and
biomedical research. Of particular importance is the fact that ferrocenes with planar chirality …

Ligand‐Enabled PdII‐Catalyzed Iterative γ‐C(sp3)−H Arylation of Free Aliphatic Acid

P Dolui, J Das, HB Chandrashekar… - Angewandte Chemie …, 2019 - Wiley Online Library
C− H functionalization of aliphatic carboxylic acids without attaching exogenous auxiliary
has been so far limited at the proximal β‐position. In this work, we demonstrate a ligand …

Transition Metal‐Catalyzed C− H Bond Functionalizations by Use of Sulfur‐Containing Directing Groups

KX Tang, CM Wang, TH Gao, L Chen… - Advanced Synthesis …, 2019 - Wiley Online Library
Transition metal‐catalyzed direct functionalization of C− H bonds is an economical and
efficient way to construct complex molecules that is currently attracting tremendous attention …

Assembling a Hybrid Pd Catalyst from a Chiral Anionic CoIII Complex and Ligand for Asymmetric C(sp3)–H Functionalization

HJ Jiang, XM Zhong, J Yu, Y Zhang… - Angewandte Chemie …, 2019 - Wiley Online Library
An unusual hybrid palladium catalyst containing an anionic chiral CoIII complex and a chiral
phosphoramidite ligand shows a high capacity for catalyzing asymmetric thioamide‐directed …

Thioketone-directed rhodium (I) catalyzed enantioselective CH bond arylation of ferrocenes

ZJ Cai, CX Liu, Q Wang, Q Gu, SL You - Nature communications, 2019 - nature.com
Planar chiral ferrocenes have received great attention in both academia and industry.
Although remarkable progresses have been made over the past decade, the development of …

Micellar Catalysis for Ruthenium(II)‐Catalyzed C−H Arylation: Weak‐Coordination‐Enabled C−H Activation in H2O

SR Yetra, T Rogge, S Warratz, J Struwe… - Angewandte Chemie …, 2019 - Wiley Online Library
Chemoselective C− H arylations were accomplished through micellar catalysis by a versatile
single‐component ruthenium catalyst. The strategy provided expedient access to C− H …

Copper-catalyzed 8-aminoquinoline assisted aryl chalcogenation of ferroceneamide with aryl disulfides, diselenides, and ditellurides

M Sattar, M Shareef, K Patidar… - The Journal of Organic …, 2018 - ACS Publications
A synthetic method has been developed for the synthesis of unsymmetrical ferrocene aryl
chalcogenides by C–H activation of ferroceneamide using 8-aminoquinoline as a directing …

Native functional group directed distal C (sp 3)–H activation of aliphatic systems

S Saha, J Das, SA Al-Thabaiti, SM Albukhari… - Catalysis Science & …, 2023 - pubs.rsc.org
Aliphatic systems are ubiquitous in numerous natural products and pharmacoactive
compounds. Selective remote C–H functionalization of such aliphatic chains is of great …

Synthesis of Substituted Naphtho[1,8-bc]thiopyrans by Sulfhydryl-Directed Rhodium-Catalyzed peri-Selective C–H Bond Activation and Cyclization of Naphthalene-1 …

K Yan, M Liu, J Wen, S Wang, J Li, H Wang - Organic Letters, 2020 - ACS Publications
The sulfhydryl-directed peri-selective C–H bond activation and tandem cyclization of
naphthalene-1-thiols with alkynes proceed efficiently. Most products of naphthothiopyrans …