Sustainable protocols for direct C–H bond arylation of (hetero) arenes
G Albano, A Punzi, MAM Capozzi, GM Farinola - Green Chemistry, 2022 - pubs.rsc.org
Direct C–H bond arylation of (hetero) arenes is a very convenient approach for the synthesis
of a wide variety of molecular targets, including compounds of pharmaceutical interest and π …
of a wide variety of molecular targets, including compounds of pharmaceutical interest and π …
Asymmetric C–H bond functionalization of ferrocenes: new opportunities and challenges
CX Liu, Q Gu, SL You - Trends in Chemistry, 2020 - cell.com
Ferrocene is of great significance in the fields of organic synthesis, materials science, and
biomedical research. Of particular importance is the fact that ferrocenes with planar chirality …
biomedical research. Of particular importance is the fact that ferrocenes with planar chirality …
Ligand‐Enabled PdII‐Catalyzed Iterative γ‐C(sp3)−H Arylation of Free Aliphatic Acid
P Dolui, J Das, HB Chandrashekar… - Angewandte Chemie …, 2019 - Wiley Online Library
C− H functionalization of aliphatic carboxylic acids without attaching exogenous auxiliary
has been so far limited at the proximal β‐position. In this work, we demonstrate a ligand …
has been so far limited at the proximal β‐position. In this work, we demonstrate a ligand …
Transition Metal‐Catalyzed C− H Bond Functionalizations by Use of Sulfur‐Containing Directing Groups
KX Tang, CM Wang, TH Gao, L Chen… - Advanced Synthesis …, 2019 - Wiley Online Library
Transition metal‐catalyzed direct functionalization of C− H bonds is an economical and
efficient way to construct complex molecules that is currently attracting tremendous attention …
efficient way to construct complex molecules that is currently attracting tremendous attention …
Assembling a Hybrid Pd Catalyst from a Chiral Anionic CoIII Complex and Ligand for Asymmetric C(sp3)–H Functionalization
HJ Jiang, XM Zhong, J Yu, Y Zhang… - Angewandte Chemie …, 2019 - Wiley Online Library
An unusual hybrid palladium catalyst containing an anionic chiral CoIII complex and a chiral
phosphoramidite ligand shows a high capacity for catalyzing asymmetric thioamide‐directed …
phosphoramidite ligand shows a high capacity for catalyzing asymmetric thioamide‐directed …
Thioketone-directed rhodium (I) catalyzed enantioselective CH bond arylation of ferrocenes
Planar chiral ferrocenes have received great attention in both academia and industry.
Although remarkable progresses have been made over the past decade, the development of …
Although remarkable progresses have been made over the past decade, the development of …
Micellar Catalysis for Ruthenium(II)‐Catalyzed C−H Arylation: Weak‐Coordination‐Enabled C−H Activation in H2O
SR Yetra, T Rogge, S Warratz, J Struwe… - Angewandte Chemie …, 2019 - Wiley Online Library
Chemoselective C− H arylations were accomplished through micellar catalysis by a versatile
single‐component ruthenium catalyst. The strategy provided expedient access to C− H …
single‐component ruthenium catalyst. The strategy provided expedient access to C− H …
Copper-catalyzed 8-aminoquinoline assisted aryl chalcogenation of ferroceneamide with aryl disulfides, diselenides, and ditellurides
M Sattar, M Shareef, K Patidar… - The Journal of Organic …, 2018 - ACS Publications
A synthetic method has been developed for the synthesis of unsymmetrical ferrocene aryl
chalcogenides by C–H activation of ferroceneamide using 8-aminoquinoline as a directing …
chalcogenides by C–H activation of ferroceneamide using 8-aminoquinoline as a directing …
Native functional group directed distal C (sp 3)–H activation of aliphatic systems
Aliphatic systems are ubiquitous in numerous natural products and pharmacoactive
compounds. Selective remote C–H functionalization of such aliphatic chains is of great …
compounds. Selective remote C–H functionalization of such aliphatic chains is of great …
Synthesis of Substituted Naphtho[1,8-bc]thiopyrans by Sulfhydryl-Directed Rhodium-Catalyzed peri-Selective C–H Bond Activation and Cyclization of Naphthalene-1 …
K Yan, M Liu, J Wen, S Wang, J Li, H Wang - Organic Letters, 2020 - ACS Publications
The sulfhydryl-directed peri-selective C–H bond activation and tandem cyclization of
naphthalene-1-thiols with alkynes proceed efficiently. Most products of naphthothiopyrans …
naphthalene-1-thiols with alkynes proceed efficiently. Most products of naphthothiopyrans …