Rare-earth metal complexes as catalysts for ring-opening polymerization of cyclic esters

DM Lyubov, AO Tolpygin, AA Trifonov - Coordination Chemistry Reviews, 2019 - Elsevier
Rare-earth metal complexes as catalysts for ring-opening polymerization of cyclic esters -
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Biocompatible initiators for lactide polymerization

RH Platel, LM Hodgson, CK Williams - Polymer Reviews, 2008 - Taylor & Francis
The review summarizes recent developments in the preparation and use of new initiators for
the ring opening polymerization of lactide. The review compares different classes of initiator …

Polymerization of lactide and related cyclic esters by discrete metal complexes

BJ O'Keefe, MA Hillmyer, WB Tolman - Journal of the Chemical Society …, 2001 - pubs.rsc.org
This perspective highlights recent research on the preparation of polyesters by the ring-
opening polymerization of cyclic esters employing well-characterized metal complexes …

Non-cyclopentadienyl ancillaries in organogroup 3 metal chemistry: a fine balance in ligand design

WE Piers, DJH Emslie - Coordination Chemistry Reviews, 2002 - Elsevier
Over the past decade, several groups have targeted well-defined organometallic Group 3
metal complexes with ancillary ligand supporting environments alternative to the ubiquitous …

Titanium and zirconium complexes of dianionic and trianionic amine− phenolate-type ligands in catalysis of lactide polymerization

S Gendler, S Segal, I Goldberg, Z Goldschmidt… - Inorganic …, 2006 - ACS Publications
The synthesis of alkoxotitanium (IV) and-zirconium (IV) complexes of seven chelating
tetradentate di-or trianionic amine− phenolate ligands belonging to three families and their …

Guanidinate and amidopyridinate rare-earth complexes: Towards highly reactive alkyl and hydrido species

AA Trifonov - Coordination Chemistry Reviews, 2010 - Elsevier
The review summarizes advances in the chemistry of organo rare-earth complexes
containing bulky guanidinate and amidopyridinate ligands. The methods of synthesis …

Polymerization of 1, 3-conjugated dienes with rare-earth metal precursors

Z Zhang, D Cui, B Wang, B Liu, Y Yang - Molecular catalysis of rare-earth …, 2010 - Springer
This chapter surveys the publications except patents related to cis-1, 4-, trans-1, 4-, 3, 4-
regio-, and stereoselective polymerizations of 1, 3-conjugated dienes with rare-earth metal …

Titanium alkoxides as initiators for the controlled polymerization of lactide

Y Kim, GK Jnaneshwara, JG Verkade - Inorganic chemistry, 2003 - ACS Publications
Fourteen titanium alkoxides were synthesized for comparison of their catalytic properties in
the bulk and solution polymerization of lactide (LA). In bulk polymerizations, they are …

Stereoselective ring-opening polymerization of racemic lactide using alkoxy-amino-bis (phenolate) group 3 metal complexes

CX Cai, A Amgoune, CW Lehmann… - Chemical …, 2004 - pubs.rsc.org
Stereoselective ring-opening polymerization of racemic lactide using alkoxy-amino-bis(phenolate)
group 3 metal complexes - Chemical Communications (RSC Publishing) DOI:10.1039/B314030J …

Controlled ring-opening polymerization of lactide by group 3 metal complexes

A Amgoune, CM Thomas… - Pure and Applied …, 2007 - degruyter.com
In this review, attention is focused on the use of group 3 metal complexes for the ring-
opening polymerization (ROP) of lactide to give polylactides (PLAs). Synthesis of PLAs has …