[HTML][HTML] Preparation, acyl migration and applications of the acylglycerols and their isomers: A review

Y Mao, YY Lee, X Xie, Y Wang, Z Zhang - Journal of Functional Foods, 2023 - Elsevier
Acylglycerols in natural oils includes monoacylglycerols (MAG), diacylglycerols (DAG) and
triacylglycerols (TAG). Each acylglycerol possesses different isomers, which results in …

[HTML][HTML] Analysis of the effect of recent reformulation strategies on the crystallization behaviour of cocoa butter and the structural properties of chocolate

H Ewens, L Metilli, E Simone - Current Research in Food Science, 2021 - Elsevier
Chocolate is a complex soft material characterized by solid particles (cocoa powder, milk
solid particles and sugar crystals) dispersed in a crystallized fat matrix mostly composed of …

Molecular origins of polymorphism in cocoa butter

SM Ghazani, AG Marangoni - Annual Review of Food Science …, 2021 - annualreviews.org
Cocoa butter displays complex crystallization behavior and six crystal polymorphic forms.
Although the crystal structure of cocoa butter has been studied extensively, the molecular …

Role of stearic acid as the crystal habit modifier in candelilla wax-groundnut oil oleogels

D Chaturvedi, D Bharti, S Dhal, D Sahu, H Behera… - ChemEngineering, 2023 - mdpi.com
This study investigated the effects of incorporating stearic acid (SAC) in candelilla wax (CW)
and groundnut oil (GO) oleogel with potential health benefits as an alternative to saturated …

StOSt-rich fats in the manufacture of heat-stable chocolates and their potential impacts on fat bloom behaviors

J Jin, Q Jin, CC Akoh, X Wang - Trends in Food Science & Technology, 2021 - Elsevier
Background Chocolate softening and fat bloom are the main defects in many tropical and
subtropical markets. Incorporation of hard fats with similar triacylglycerol-type to cocoa …

[HTML][HTML] Formation of dark chocolate fats with improved heat stability and desirable miscibility by blending cocoa butter with mango kernel fat stearin and hard palm …

Y Chen, Y Wang, J Jin, Q Jin, CC Akoh, X Wang - LWT, 2022 - Elsevier
Softening and fat bloom are serious quality defects for dark chocolates, which mainly results
from insufficient melting characteristics of cocoa butter (CB) and more likely to occur in …

An insight into the solid-state miscibility of triacylglycerol crystals

J Macridachis-González, L Bayés-García, T Calvet - Molecules, 2020 - mdpi.com
The crystallization properties of triacylglycerols (TAGs) strongly determine the functional
properties of natural lipids. The polymorphic and mixing phase behavior of TAG molecules …

Kinetics crystallization and polymorphism of cocoa butter throughout the spontaneous fermentation process

EM Castro-Alayo, L Torrejón-Valqui… - Foods, 2022 - mdpi.com
The spontaneous fermentation process of Criollo cocoa is studied for its importance in the
development of chocolate aroma precursors. This research supports the importance of …

[HTML][HTML] A synchrotron X-ray scattering study of the crystallization behavior of mixtures of confectionary triacylglycerides: Effect of chemical composition and shear on …

E Simone, M Rappolt, H Ewens, T Rutherford… - Food Research …, 2024 - Elsevier
Cocoa butter equivalents (CBE) are mixtures of triglycerides from multiple sources (eg,
sunflower oil, mango kernel and sal), which resemble cocoa butter (CB) in both physical and …

Crystallization and polymorphic behaviors of cocoa butter alternatives: A review

MR Ramos Ramos, VA García Londoño… - Journal of the …, 2023 - Wiley Online Library
Although cocoa butter (CB) has remarkable physical properties, its high price, growing
difficulties, and increased consumption have been the main incentive to explore alternatives …