Oxygen is ubiquitous. It comprises nearly 50% of the Earth's crust and is an essential
component in metabolic pathways in all higher organisms. 1 It was first identified by Carl …

This review discusses the heteroatom-containing dioxiranes in organic chemistry.
Heteroatom-containing dioxiranes are three-membered ring peroxides with the form XO2 …

This paper describes the synthesis, characterization, reactivity, and electrochemistry of
monolayer-protected clusters (MPCs) of palladium that are passivated by monolayers of …

A coordination-assisted pyrolysis procedure was adopted to encapsulate palladium (Pd)
nanoparticles in a mesoporous carbonaceous matrix. X-ray diffraction and transmission …

Ni-containing superoxide dismutase (NiSOD) is the most recently discovered member of the
class of metalloenzymes that detoxify the superoxide radical in aerobic organisms. In this …

The main developments in rational construction of chiral metallo-aggregates based on
octahedral metal complexes with 2-aminoethanethiolate (aet) or l-cysteinate (l-cys), as well …

The diamino-dithiolato N2S2 ligand N, N '-bis-2-methyl-mercaptopropyl-N, N '-
dimethylethylenediamine, H2 (bmmp-dmed), and its nickel (1) and zinc (2) complexes have …

The distal nickel site of acetyl-CoA synthase (Nid-ACS) and reduced nickel superoxide
dismutase (Ni-SOD) display similar square-planar NiIIN2S2 coordination environments. One …

[Pd (bpy)(bdt)], 2 (bpy= 2, 2 '-bipyridine, bdt= 1, 2-benzenedithiolate), was prepared in good
yield by the reaction of bdtNa2 with [(bpy) PdCl2] in DMSO. The analogous nickel complex …

Metal thiolate complexes can act as photosensitizers for the generation of singlet oxygen,
quenchers of singlet oxygen, and they may undergo chemical reactions with singlet oxygen …