Hidden diversity of vacancy networks in Prussian blue analogues
Prussian blue analogues (PBAs) are a diverse family of microporous inorganic solids,
known for their gas storage ability, metal-ion immobilization, proton conduction, and stimuli …
known for their gas storage ability, metal-ion immobilization, proton conduction, and stimuli …
Switchable Metal Sites in Metal–Organic Framework MFM‐300 (Sc): Lewis Acid Catalysis Driven by Metal–Hemilabile Linker Bond Dynamics
Uncommon reversible guest‐induced metal‐hemilabile linker bond dynamics in MOF MFM‐
300 (Sc) was unraveled to switch on/switch off catalytic open metal sites. The catalytic …
300 (Sc) was unraveled to switch on/switch off catalytic open metal sites. The catalytic …
A guide to modern methods for poly (thio) ether synthesis using Earth-abundant metals
Polyethers and polythioethers have a long and storied history dating back to the start of
polymer science as a distinct field. As such, these materials have been utilized in a wide …
polymer science as a distinct field. As such, these materials have been utilized in a wide …
Selective Photocatalytic Dehydrogenation of Formic Acid by an In Situ-Restructured Copper-Postmetalated Metal–Organic Framework under Visible Light
Formic acid is considered as one of the most promising liquid organic hydrogen carriers. Its
catalytic dehydrogenation process generally suffers from low activity, low reaction selectivity …
catalytic dehydrogenation process generally suffers from low activity, low reaction selectivity …
Organic carbonates as green and sustainable complexing agents for double metal cyanide catalysts for the synthesis of polyether and poly (ether-carbonate) polyols
We investigated various linear carbonates, including dimethyl carbonate and diethyl
carbonate, and cyclic carbonates such as ethylene carbonate, propylene carbonate (PC) …
carbonate, and cyclic carbonates such as ethylene carbonate, propylene carbonate (PC) …
Organonitriles as complexing agents for the double metal cyanide-catalyzed synthesis of polyether, polyester, and polycarbonate polyols
A series of double metal cyanide (DMC) catalysts prepared using nitrile compounds as
complexing agents (CAs) was employed for the synthesis of polyether, polyester, and …
complexing agents (CAs) was employed for the synthesis of polyether, polyester, and …
[HTML][HTML] Prussian blue analogs as catalysts for the fixation of CO2 to glycidol to produce glycerol carbonate and multibranched polycarbonate polyols
A series of Prussian blue analogs (PBAs) having a range of crystal structures and
compositions was investigated as heterogeneous catalysts for the fixation of carbon dioxide …
compositions was investigated as heterogeneous catalysts for the fixation of carbon dioxide …
Copper–cobalt double metal cyanides as green catalysts for phosphoramidate synthesis
A Fonseca, AL Bugaev, AY Pnevskaya… - Communications …, 2023 - nature.com
Phosphoramidates are common and widespread backbones of a great variety of fine
chemicals, pharmaceuticals, additives and natural products. Conventional approaches to …
chemicals, pharmaceuticals, additives and natural products. Conventional approaches to …
[HTML][HTML] Synthesis, Structure, and Actual Applications of Double Metal Cyanide Catalysts
IE Nifant'ev, PV Ivchenko - International Journal of Molecular Sciences, 2024 - mdpi.com
Double metal cyanide (DMC) complexes represent a unique family of materials with an open
framework structure. The main current application of these complexes in chemical industry is …
framework structure. The main current application of these complexes in chemical industry is …
Highly active heterogeneous double metal cyanide catalysts for ring-opening polymerization of cyclic monomers
A series of heterogeneous Zn-Co double metal cyanide (DMC) catalysts were investigated
for ring-opening polymerization (ROP) of various cyclic monomers. Notably, inexpensive …
for ring-opening polymerization (ROP) of various cyclic monomers. Notably, inexpensive …