Metal complexes of porphyrinoids containing nonpyrrolic heterocycles

DW Thuita, C Brückner - Chemical Reviews, 2022 - ACS Publications
The replacement of one or more pyrrolic building block (s) of a porphyrin by a nonpyrrolic
heterocycle leads to the formation of so-called pyrrole-modified porphyrins (PMPs) …

Recent advances on visible light Triphenylamine-based photoinitiators of polymerization

F Dumur - European Polymer Journal, 2022 - Elsevier
During the past decades, visible light photoinitiators have been extensively studied due to
the development of cheap and energy-saving irradiation sources, namely light-emitting …

Circularly polarized luminescence from axially chiral BODIPY DYEmers: an experimental and computational study

F Zinna, T Bruhn, CA Guido, J Ahrens… - … A European Journal, 2016 - Wiley Online Library
With our new home‐built circularly polarized luminescence (CPL) instrument, we measured
fluorescence and CPL spectra of the enantiomeric pairs of two quasi‐isomeric BODIPY …

The Breaking and Mending of meso-Tetraarylporphyrins: Transmuting the Pyrrolic Building Blocks

C Bruckner - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Naturally occurring porphyrins and hydroporphyrins vary with respect to their
ring substituents and oxidation states, but their tetrapyrrolic frameworks remain fully …

[HTML][HTML] Indane-1, 3-Dione: From Synthetic Strategies to Applications

C Pigot, D Brunel, F Dumur - Molecules, 2022 - mdpi.com
Indane-1, 3-dione is a versatile building block used in numerous applications ranging from
biosensing, bioactivity, bioimaging to electronics or photopolymerization. In this review, an …

A Rapid “off-on” copper-induced AIE active sensor for fluorimetric detection of cysteine

Y Cai, J Fang, H Zhu, W Qin, Y Cao, H Yu… - Sensors and Actuators B …, 2020 - Elsevier
As a sulfur-containing amino acid, cysteine (Cys) plays a crucial role in life process.
Abnormal Cys content can trigger a series of diseases, such as developmental delay, hair …

Porphyrin macrocycle modification: Pyrrole ring-contracted or-expanded porphyrinoids

LD Costa, JIT Costa, AC Tomé - Molecules, 2016 - mdpi.com
In recent years, several synthetic strategies aiming at the peripheral functionalization of
porphyrins were developed. Particularly interesting are those involving the modification of β …

Versatile synthetic route for β-functionalized chlorins and porphyrins by varying the size of michael donors: syntheses, photophysical, and electrochemical redox …

N Chaudhri, N Grover, M Sankar - Inorganic Chemistry, 2017 - ACS Publications
One-pot facile synthesis and characterization of novel β-substituted meso-
tetraphenylporphyrins and/or chlorins were described. The high regioselective reactivity of …

Nickel-Induced Skeletal Rearrangement of Free Base trans-Chlorins into Monofused NiII-Porphyrins: Synthesis, Structural, Spectral, and Electrochemical Redox …

N Chaudhri, N Grover, M Sankar - Inorganic Chemistry, 2018 - ACS Publications
Several ruffled β-to-ortho-phenyl monofused metalloporphyrins (MIIMFPs) with 1, 3-
indanedione functionality have been synthesized by oxidative fusion of free base trans …

Axial, helical, and planar chirality in directly linked basket-handle porphyrin arrays

AC Gehrold, T Bruhn, G Bringmann - The Journal of Organic …, 2016 - ACS Publications
The single-electron oxidative dimerization of basket-handle porphyrins (BHPs) with different
coordinated metal ions [Cu (II), Ni (II), Pd (II), Zn (II)] yielded directly meso-meso linked …