Classical and nonclassical nucleation and growth mechanisms for nanoparticle formation
All solid materials are created via nucleation. In this evolutionary process, nuclei form in
solution or at interfaces, expand by monomeric growth and oriented attachment, and …
solution or at interfaces, expand by monomeric growth and oriented attachment, and …
The Current Understanding of Mechanistic Pathways in Zeolite Crystallization
AJ Mallette, K Shilpa, JD Rimer - Chemical Reviews, 2024 - ACS Publications
Zeolite catalysts and adsorbents have been an integral part of many commercial processes
and are projected to play a significant role in emerging technologies to address the …
and are projected to play a significant role in emerging technologies to address the …
Controlling nucleation pathways in zeolite crystallization: seeding conceptual methodologies for advanced materials design
A core objective of synthesizing zeolites for widespread applications is to produce materials
with properties and corresponding performances that exceed conventional counterparts …
with properties and corresponding performances that exceed conventional counterparts …
Silanol-engineered nonclassical growth of zeolite nanosheets from oriented attachment of amorphous protozeolite nanoparticles
Q Zhang, J Li, X Wang, G He, L Li, J Xu… - Journal of the …, 2023 - ACS Publications
Zeolite nonclassical growth via particle attachment has been proposed for two decades, yet
the attachment mechanism and kinetic regulation remain elusive. Here, nonclassical growth …
the attachment mechanism and kinetic regulation remain elusive. Here, nonclassical growth …
Synthesis of NaA zeolite via the mesoscale reorganization of submolten salt depolymerized kaolin: A mechanistic study
Deep understanding of the formation mechanism is crucial to the rational design and
controllable synthesis of zeolites with desired pore architecture and acidity. Herein, we take …
controllable synthesis of zeolites with desired pore architecture and acidity. Herein, we take …
Spontaneous pillaring of pentasil zeolites
Conventional methods to prepare hierarchical zeolites depend upon the use of organic
structure‐directing agents and often require multiple synthesis steps with limited product …
structure‐directing agents and often require multiple synthesis steps with limited product …
Growth defects of organic crystals: A review
M Li, C Zhang, M Li, F Liu, L Zhou, Z Gao, J Sun… - Chemical Engineering …, 2022 - Elsevier
During the growth of organic crystals, crystal defects can be formed. Microscopic defects,
which include point, line, and planar defects, appearing as vacancies, growth dislocations …
which include point, line, and planar defects, appearing as vacancies, growth dislocations …
Impact of a polymer modifier on directing the non-classical crystallization pathway of TS-1 zeolite: accelerating nucleation and enriching active sites
The crystallization process directly affects the physicochemical properties and active centers
of zeolites; however, controllable tuning of the zeolite crystallization process remains a …
of zeolites; however, controllable tuning of the zeolite crystallization process remains a …
Surface Diffusion Barriers and Catalytic Activity Driven by Terminal Groups at Zeolite Catalysts
Defects that commonly exist on the surface of zeolites pose notable mass transport
constraints and influence the catalytic performance. The mechanism underlying the surface …
constraints and influence the catalytic performance. The mechanism underlying the surface …
Insights into solid-to-solid transformation of MOF amorphous phases
YA Mezenov, S Bruyere, A Krasilin… - Inorganic …, 2022 - ACS Publications
Metal–organic frameworks (MOFs) have been recently explored as crystalline solids for
conversion into amorphous phases demonstrating non-specific mechanical, catalytic, and …
conversion into amorphous phases demonstrating non-specific mechanical, catalytic, and …