Classical and nonclassical nucleation and growth mechanisms for nanoparticle formation

YS Jun, Y Zhu, Y Wang, D Ghim, X Wu… - Annual Review of …, 2022 - annualreviews.org
All solid materials are created via nucleation. In this evolutionary process, nuclei form in
solution or at interfaces, expand by monomeric growth and oriented attachment, and …

The Current Understanding of Mechanistic Pathways in Zeolite Crystallization

AJ Mallette, K Shilpa, JD Rimer - Chemical Reviews, 2024 - ACS Publications
Zeolite catalysts and adsorbents have been an integral part of many commercial processes
and are projected to play a significant role in emerging technologies to address the …

Controlling nucleation pathways in zeolite crystallization: seeding conceptual methodologies for advanced materials design

R Jain, AJ Mallette, JD Rimer - Journal of the American Chemical …, 2021 - ACS Publications
A core objective of synthesizing zeolites for widespread applications is to produce materials
with properties and corresponding performances that exceed conventional counterparts …

Silanol-engineered nonclassical growth of zeolite nanosheets from oriented attachment of amorphous protozeolite nanoparticles

Q Zhang, J Li, X Wang, G He, L Li, J Xu… - Journal of the …, 2023 - ACS Publications
Zeolite nonclassical growth via particle attachment has been proposed for two decades, yet
the attachment mechanism and kinetic regulation remain elusive. Here, nonclassical growth …

Synthesis of NaA zeolite via the mesoscale reorganization of submolten salt depolymerized kaolin: A mechanistic study

X Chen, Y Wang, C Wang, J Xu, T Li, Y Yue, X Bi… - Chemical Engineering …, 2023 - Elsevier
Deep understanding of the formation mechanism is crucial to the rational design and
controllable synthesis of zeolites with desired pore architecture and acidity. Herein, we take …

Spontaneous pillaring of pentasil zeolites

R Jain, A Chawla, N Linares… - Advanced …, 2021 - Wiley Online Library
Conventional methods to prepare hierarchical zeolites depend upon the use of organic
structure‐directing agents and often require multiple synthesis steps with limited product …

Growth defects of organic crystals: A review

M Li, C Zhang, M Li, F Liu, L Zhou, Z Gao, J Sun… - Chemical Engineering …, 2022 - Elsevier
During the growth of organic crystals, crystal defects can be formed. Microscopic defects,
which include point, line, and planar defects, appearing as vacancies, growth dislocations …

Impact of a polymer modifier on directing the non-classical crystallization pathway of TS-1 zeolite: accelerating nucleation and enriching active sites

J Zhang, R Bai, Y Zhou, Z Chen, P Zhang, J Li… - Chemical Science, 2022 - pubs.rsc.org
The crystallization process directly affects the physicochemical properties and active centers
of zeolites; however, controllable tuning of the zeolite crystallization process remains a …

Surface Diffusion Barriers and Catalytic Activity Driven by Terminal Groups at Zeolite Catalysts

M Gao, H Li, Y Tian, J Yu, M Ye, Z Liu - ACS Catalysis, 2023 - ACS Publications
Defects that commonly exist on the surface of zeolites pose notable mass transport
constraints and influence the catalytic performance. The mechanism underlying the surface …

Insights into solid-to-solid transformation of MOF amorphous phases

YA Mezenov, S Bruyere, A Krasilin… - Inorganic …, 2022 - ACS Publications
Metal–organic frameworks (MOFs) have been recently explored as crystalline solids for
conversion into amorphous phases demonstrating non-specific mechanical, catalytic, and …