The review presents a bird-eye view on the state of research in the field of giant
nonbiological discrete metal complexes and ions of nanometer size, which are structurally …

The high-nuclearity silver (I) clusters, a novel class of supramolecular assembly of silver (I)
complexes, were usually prepared by incorporating silver ions with various ligands. Notably …

Convenient generation of stable superatomic silver clusters and their systematic site-specific
tailoring and directional assembly present an enduring and significant challenge. In this …

To realize the molecular design of new functional silver (I) clusters, a new synthetic
approach has been proposed, by which the weakly coordinating ligands NO3–in a Ag20 …

Silver chalcogenolate cluster assembled materials (SCAMs) are a category of promising
light‐emitting materials the luminescence of which can be modulated by variation of their …

Although there has been an upsurge of interest in anisotropic assembly of inorganic
nanoparticles, atomically precise self-assembly of anisotropic metal clusters is extremely …

Thiacalix [4] arenes as a family of promising ligands have been widely used to construct
polynuclear metal clusters, but scarcely employed in silver nanoclusters. Herein, an anion …

Metalloligand strategy has been well recognized in the syntheses of heterometallic
coordination polymers; however, such a strategy used in the assembly of silver nanoclusters …

Stepwise assembly starting from a preassembled metalloligand is a promising approach to
obtain otherwise unattainable silver nanoclusters, but hard to be intrinsically identified due …

Control over core structure is much more challenging than that over shell structure in core–
shell silver nanoclusters. Herein, two isostructural chalcogen-mediated [Ag6Z4@ Ag36](Z …