Readily accessible and shelf-stable 1, 2, 3-triazole and its analogues such as pyridotriazole,
triazoloindole, benzotriazole, and thiadiazole exist in equilibrium with their ring-opened …

Olefin 1, 2-difunctionalization has emerged as a popular strategy within modern synthetic
chemistry for the synthesis of vicinal amino alcohols and derivatives. The advantage of this …

An efficient diastereoselective rhodium catalyzed synthesis of indolines possessing two
contiguous tetrasubstituted carbon centers has been achieved with good to excellent yields …

An efficient and novel rhodium-catalyzed transannulation of N-sulfonyl-1, 2, 3-triazoles with
in situ generated o-quinone methides (o-QMs) from 2-hydroxybenzyl alcohols has been …

The enantioselective intermolecular sp3 C–H functionalization at the allylic and benzylic
positions was achieved using rhodium-catalyzed reactions with 4-phenyl-N …

Using N-sulfonyl triazoles as substrates, compounds as diverse as 2-imino tetrahydrofurans,
13-and 15-membered ring aza-macrocycles can be prepared selectively via formal [1+ 4],[5+ …

The synthesis of β-arylpyrrolidines via a catalytic enantioselective intermolecular allylic C
(sp) 3–H functionalization of trans-alkenes followed by immediate reduction, ozonolysis, and …

Herein we describe a novel Rh (II)-catalyzed intramolecular transannulation reaction of 1, 2,
3-triazolyl carbamates to access functionalized 4-aminooxazolidinones under operationally …

In order to obtain new supramolecular ligands that build up around a zinc‐porphyrin
scaffold, we envisioned to access sulfonyl triazole intermediates by well‐known copper …

An efficient rhodium-catalyzed synthesis of dihydro-3, 1-benzoxazine derivatives has been
accomplished from aniline-derived 1, 3-amino alcohols and N-sulfonyl-1, 2, 3-triazole. The …