Soot inception: Carbonaceous nanoparticle formation in flames

JW Martin, M Salamanca, M Kraft - Progress in Energy and Combustion …, 2022 - Elsevier
The route by which gas-phase molecules in hydrocarbon flames form condensed-phase
carbonaceous nanoparticles (incipient soot) is reviewed. These products of incomplete …

Combustion chemistry of aromatic hydrocarbons

H Jin, W Yuan, W Li, J Yang, Z Zhou, L Zhao… - Progress in Energy and …, 2023 - Elsevier
Aromatic hydrocarbons are important components of petroleum-based transportation fuels,
biomass, coal, and solid waste, etc. The reaction kinetics of aromatic hydrocarbons largely …

Molecular elucidating of an unusual growth mechanism for polycyclic aromatic hydrocarbons in confined space

N Wang, Y Zhi, Y Wei, W Zhang, Z Liu, J Huang… - Nature …, 2020 - nature.com
Extension and clustering of polycyclic aromatic hydrocarbons (PAHs) are key mechanistic
steps for coking and deactivation in catalysis reactions. However, no unambiguous …

Vacuum ultraviolet photoionization on-line mass spectrometry: Instrumentation developments and applications

M Dang, R Liu, F Dong, B Liu, K Hou - TrAC Trends in Analytical Chemistry, 2022 - Elsevier
On-line mass spectrometry (MS) techniques provide high time resolution for insight into
chemical changes, while eliminating the potential artifacts acquired during sample collection …

Promotion of particle formation by resonance-stabilized radicals during hydrocarbon pyrolysis

JA Rundel, CM Thomas, PE Schrader, KR Wilson… - Combustion and …, 2022 - Elsevier
We measured aerosol mass spectra and mobility size distributions of particles formed during
the pyrolysis of ethylene, indene, and a mixture of ethylene with a small amount of indene …

First aromatic ring formation by the radical-chain reaction of vinylacetylene and propargyl

H Jin, L Xing, D Liu, J Hao, J Yang, A Farooq - Combustion and Flame, 2021 - Elsevier
Recent investigations illustrated that clustering of hydrocarbons by radical-chain reaction
(CHRCR) mechanism provides key mechanistic steps for the rapid synthesis of polycyclic …

C7 reaction mechanism and its self-imitation in the kinetic modeling of PAH formation

H Jin, A Farooq - Combustion and Flame, 2023 - Elsevier
Polycyclic aromatic hydrocarbons (PAHs), serving as critical soot precursors, are formed via
complicated chemical processes, such as the first aromatic ring formation and the aromatic …

Ultrafast 1 MHz vacuum-ultraviolet source via highly cascaded harmonic generation in negative-curvature hollow-core fibers

DE Couch, DD Hickstein, DG Winters, SJ Backus… - Optica, 2020 - opg.optica.org
Vacuum-ultraviolet (VUV) light is critical for the study of molecules and materials, but the
generation of femtosecond pulses in the VUV region at high repetition rates has proven …

[HTML][HTML] Production of aliphatic-linked polycyclic hydrocarbons during radical-driven particle formation from propyne and propene pyrolysis

JA Rundel, KO Johansson, PE Schrader… - Combustion and …, 2023 - Elsevier
We investigated the pyrolysis of propyne and propene using aerosol mass spectrometry
coupled with tunable synchrotron vacuum ultraviolet photoionization. The results show that …

Hydrogen ejection from hydrocarbons: Characterization and relevance in soot formation and interstellar chemistry

J Hendrix, D Hait, HA Michelsen… - Proceedings of the …, 2024 - pnas.org
Polycyclic aromatic hydrocarbons (PAHs) play a major role in the chemistry of combustion,
pyrolysis, and the interstellar medium. Production (or activation) of radical PAHs and …