The biologically relevant coordination chemistry of iron and nitric oxide: electronic structure and reactivity

N Lehnert, E Kim, HT Dong, JB Harland… - Chemical …, 2021 - ACS Publications
Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …

Precious metal-free approach to hydrogen electrocatalysis for energy conversion: From mechanism understanding to catalyst design

T Wang, H Xie, M Chen, A D'Aloia, J Cho, G Wu, Q Li - Nano Energy, 2017 - Elsevier
Hydrogen (H 2) is the most promising green energy resources to replace conventional fossil
fuels due to the high mass energy density and renewability. The hydrogen evolution reaction …

Water‐soluble polymers with appending porphyrins as bioinspired catalysts for the hydrogen evolution reaction

L Xie, J Tian, Y Ouyang, X Guo… - Angewandte Chemie …, 2020 - Wiley Online Library
Molecular design to improve catalyst performance is significant but challenging. In enzymes,
residue groups that are close to reaction centers play critical roles in regulating activities …

Electrocatalytic hydrogen evolution with gallium hydride and ligand-centered reduction

N Wang, H Lei, Z Zhang, J Li, W Zhang, R Cao - Chemical Science, 2019 - pubs.rsc.org
GaIII chloride tetrakis (pentafluorophenyl) porphyrin (1) was synthesized and shown to be a
highly active and stable post-transition metal-based electrocatalyst for the hydrogen …

Bioinorganic Chemistry of the Natural [Fe(NO)2] Motif: Evolution of a Functional Model for NO-Related Biomedical Application and Revolutionary Development of a …

TT Lu, YM Wang, CH Hung, SJ Chiou… - Inorganic …, 2018 - ACS Publications
Identification of the distinctive electron paramagnetic resonance signal at g= 2.03 in the
yeast cells and liver of mice treated with carcinogens opened the discovery and …

Highly Efficient Hydrogen Evolution from Seawater by Biofunctionalized Exfoliated MoS2 Quantum Dot Aerogel Electrocatalysts That Is Superior to Pt

IWP Chen, CH Hsiao, JY Huang, YH Peng… - … applied materials & …, 2019 - ACS Publications
As a source of clean and sustainable energy, reliable hydrogen production requires highly
efficient and stable electrocatalysts. In recent years, molybdenum disulfide (MoS2) has been …

A PEGylated Tin Porphyrin Complex for Electrocatalytic Proton Reduction: Mechanistic Insights into Main‐Group‐Element Catalysis

A Chaturvedi, GA McCarver, S Sinha… - Angewandte Chemie …, 2022 - Wiley Online Library
Electrocatalytic proton reduction to form dihydrogen (H2) is an effective way to store energy
in the form of chemical bonds. In this study, we validate the applicability of a main‐group …

Single atomically anchored iron on graphene quantum dots for a highly efficient oxygen evolution reaction

CY Chang, AA Kashale, CM Lee, SL Chu, YF Lin… - Materials Today …, 2021 - Elsevier
Single-atom catalysts (SACs) supported on carbon-based materials are very promising for
maximizing their electrocatalytic activity. However, carbon-based SACs are primarily bonded …

Immobilized cobalt bis (benzenedithiolate) complexes: exceptionally active heterogeneous electrocatalysts for dihydrogen production from mildly acidic aqueous …

SC Eady, MM MacInnes, N Lehnert - Inorganic chemistry, 2017 - ACS Publications
A series of cobalt bis (benzenedithiolate) complexes with varying benzenedithiolate
(general abbreviation: bdt2–) ring substitutions (S2C6X42–) were prepared and adsorbed …

Insight into the Electronic Structure of Biomimetic Dinitrosyliron Complexes (DNICs): Toward the Syntheses of Amido-Bridging Dinuclear DNICs

CY Tung, YT Tseng, TT Lu, WF Liaw - Inorganic Chemistry, 2021 - ACS Publications
The ubiquitous function of nitric oxide (NO) guided the biological discovery of the natural
dinitrosyliron unit (DNIU)[Fe (NO) 2] as an intermediate/end product after Fe nitrosylation of …