Transition metal-catalysed C–H activation has emerged as an increasingly powerful platform
for molecular syntheses, enabling applications to natural product syntheses, late-stage …

The conversion of light alkanes into bulk chemicals is becoming an important challenge as it
effectively avoids the use of prefunctionalized alkylating reagents. The implementation of …

Disclosed here is the use of an iron catalyst system for an intramolecular C− H amidation
toward γ‐lactam synthesis from dioxazolone precursors.(Phthalocyanine) FeIIICl was found …

Alkanes are an abundant and inexpensive source of hydrocarbons; thus, development of
new methods to convert the hydrocarbon feedstocks to value-added chemicals is of high …

A cobalt (III)-catalyzed directed C-7 alkynylation of indolines with easily accessible
bromoalkynes has been developed. The reaction has a broad substrate scope with excellent …

A catalyst-free amino-alcoholysis depolymerization protocol was explored for the chemical
recycling of poly (bisphenol A carbonate)(BPA-PC). Under mild conditions, the initial …

Carbocation intermediacy is postulated in numerous organic transformations and provides
the foundation for retrosynthetic logics in chemical synthesis. Although a number of catalytic …

Organic azides are highly reactive, which have long established as versatile building blocks
in the assembly of structurally diverse N‐containing heterocycles. The conversion of organic …

We herein disclose the Cp* Co (III)(LX)-catalyzed amidative alkyl migration using 2, 6-
disubstituted phenyl azidoformates. Upon the cobalt–nitrenoid insertion toward the …

We report herein a series of tailored CpXRh (LX) Cl catalyst systems for the outer-sphere C–
H amidations discovered by high-throughput experimentation. Using a diverse repertoire of …