Recent developments and applications of Lewis acidic boron reagents
JR Lawson, RL Melen - 2017 - books.rsc.org
One field of organometallic chemistry that has seen great advancements over the last 20
years is that of main-group chemistry, in particular boron chemistry, that has led to a wealth …
years is that of main-group chemistry, in particular boron chemistry, that has led to a wealth …
[HTML][HTML] New chemical and stereochemical applications of organoiron complexes
AJ Fatiadi - Journal of research of the National Institute of …, 1991 - ncbi.nlm.nih.gov
The objective of this review is to provide a current overview of the rapidly developing
chemistry of organometallic complexes and particularly organoiron complexes useful in …
chemistry of organometallic complexes and particularly organoiron complexes useful in …
Generation of a bridging ethenyl ligand at a di-iron centre via carbon phosphorus bond cleavage
G Hogarth - Journal of organometallic chemistry, 1991 - Elsevier
UV irradiation of [Fe 2 (CO) 6 (μ-CO)(μ-dppm)](1) with diphenylvinylphosphine yields [Fe 2
(CO) 5 (μ-Ph 2 PCH CH 2)(μ-dppm)](2) in which the vinylphosphine acts as a bridging four …
(CO) 5 (μ-Ph 2 PCH CH 2)(μ-dppm)](2) in which the vinylphosphine acts as a bridging four …
Synthesis and x-ray crystal structure of [Fe2 (CO) 6 (. mu.-CO)(. mu.-PhC: CPhH)(. mu.-AuPPh3)]: first example of a highly asymmetric triangular Fe2Au system
Discussion The conversion of Re2Cl4 (dppm) 2 to Re2 (NCBH3) 4 (dppm) 2-(H20) 2
represents the first example of the displacement of all four chloride ligands by another …
represents the first example of the displacement of all four chloride ligands by another …
α–βAlkenyl isomerisation at diiron centres
MK Anwar, G Hogarth, OS Senturk, W Clegg… - Journal of the …, 2001 - pubs.rsc.org
α-Substituted alkenyl complexes [Fe2 (CO) 6 (μ-RCCH2)(μ-PPh2)] 1a–1e (R= Ph, Me, Prn,
Bun or But) have been prepared via regioselective hydrodimetallation of primary alkynes by …
Bun or But) have been prepared via regioselective hydrodimetallation of primary alkynes by …
The reaction of diphenylphosphine, PPh2H, with an alkyne-bridged dicobalt carbonyl complex; the synthesis crystal structure and reactivity of the complex [CO2 {μ-C …
AJM Caffyn, MJ Mays, G Conole, M McPartlin… - Journal of …, 1992 - Elsevier
The reaction between [Co 2 (μ-C 2 (CO 2 Me) 2)(CO) 6] and diphenylphosphine gives the
mono-and di-substituted complexes [Co 2 {μ-C 2}(CO 2 Me) 2 (CO) 6-n (PPh 2 H) n][n= 1 (1) …
mono-and di-substituted complexes [Co 2 {μ-C 2}(CO 2 Me) 2 (CO) 6-n (PPh 2 H) n][n= 1 (1) …
X-ray crystal structures of PPN [Fe2 (μ-CO)(CO) 6 (μ-PBu′ 2)][PPN=(PPh3) 2N+] and [Fe2 (μ-CO)(CO) 6 (μ-H)(μ-PBut2)] and structural comparison with the cluster …
HC Böttcher, H Hartung, A Krug, B Walther - Polyhedron, 1994 - Elsevier
Abstract [Fe 2 (μ-CO)(CO) 6 (μ-H)(μ-PBu t 2)](2) has been synthesized from Na [Fe 2 (μ-
CO)(CO) 6 (μ-PBu t 2)] and CH 3 COOH and structurally characterized by X-ray analysis …
CO)(CO) 6 (μ-PBu t 2)] and CH 3 COOH and structurally characterized by X-ray analysis …
Carbon carbon bond formation at diiron centres VII. New routes to anionic alkenyl-bridged diiron complexes, and reactions of the latter with propargyl chloride
New routes to [Fe 2 (CO) 6 (μ-CO)(μ-CR CR′ H)]− anions have been devised, and
compared with those previously described. Reaction of [HFe 2 (CO) 8]− with the alkynes …
compared with those previously described. Reaction of [HFe 2 (CO) 8]− with the alkynes …
Bridging alkenyl species from the protonation of ditungsten, tungsten-molybdenum and dimolybdenum transverse alkyne complexes with HCl and CF3COOH. Crystal …
GA Acum, MJ Mays, PR Raithby, GA Solan - Journal of organometallic …, 1995 - Elsevier
Some Group 6 transition metal complexes with bridging alkyne ligands [MM′(μ-
HCCMe)(CO) 4 (η5-C5H5) 2][MM′= W 21; WMo 2; Mo 23] and [WMo (μ-HCCPh)(CO) 4 (η 5 …
HCCMe)(CO) 4 (η5-C5H5) 2][MM′= W 21; WMo 2; Mo 23] and [WMo (μ-HCCPh)(CO) 4 (η 5 …
The diiron centre: Fe2 (CO) 9 and friends
G Hogarth - 2017 - books.rsc.org
From the discovery of Fe2 (CO) 9 in 1905 to the intensive post-millennium study of dithiolate-
bridged diiron complexes as biomimics of the active site of [FeFe]-hydrogenases, over the …
bridged diiron complexes as biomimics of the active site of [FeFe]-hydrogenases, over the …