Understanding surface and interfacial chemistry in functional nanomaterials via solid‐state NMR

A Marchetti, J Chen, Z Pang, S Li, D Ling… - Advanced …, 2017 - Wiley Online Library
Surface and interfacial chemistry is of fundamental importance in functional nanomaterials
applied in catalysis, energy storage and conversion, medicine, and other nanotechnologies …

Gyroscopes and the chemical literature, 2002–2020: approaches to a nascent family of molecular devices

A Ehnbom, JA Gladysz - Chemical Reviews, 2021 - ACS Publications
Research directed toward the goal of molecular gyroscopes since the coverage of a
previous review (2002) is described. Such species are a subclass of molecular rotors, which …

Fast motion of molecular rotors in metal–organic framework struts at very low temperatures

J Perego, S Bracco, M Negroni, CX Bezuidenhout… - Nature Chemistry, 2020 - nature.com
The solid state is typically not well suited to sustaining fast molecular motion, but in recent
years a variety of molecular machines, switches and rotors have been successfully …

Excited-state aromatic interactions in the aggregation-induced emission of molecular rotors

J Sturala, MK Etherington, AN Bismillah… - Journal of the …, 2017 - ACS Publications
Small, apolar aromatic groups, such as phenyl rings, are commonly included in the
structures of fluorophores to impart hindered intramolecular rotations, leading to desirable …

[HTML][HTML] Making multi-twisted luminophores produce persistent room-temperature phosphorescence

S Shen, GV Baryshnikov, Q Xie, B Wu, M Lv, H Sun… - Chemical …, 2023 - pubs.rsc.org
Multi-twisted molecules, especially those with more than four branched rotation axes, have
served as superior prototypes in diverse fields like molecular machines, optical materials …

Non‐interpenetrated single‐crystal covalent organic frameworks

L Liang, Y Qiu, WD Wang, J Han, Y Luo… - Angewandte …, 2020 - Wiley Online Library
Growth of covalent organic frameworks (COFs) as single crystals is extremely challenging.
Inaccessibility of open‐structured single‐crystal COFs prevents the exploration of structure …

Porous metal–organic polyhedral frameworks with optimal molecular dynamics and pore geometry for methane storage

Y Yan, DI Kolokolov, I Da Silva… - Journal of the …, 2017 - ACS Publications
Natural gas (methane, CH4) is widely considered as a promising energy carrier for mobile
applications. Maximizing the storage capacity is the primary goal for the design of future …

Cascading effect of large molecular motion in crystals: A topotactic polymorphic transition paves the way to topochemical polymerization

C Raju, GR Ramteke, KVJ Jose… - Journal of the American …, 2023 - ACS Publications
A topochemical polymerization governed by a topotactic polymorphic transition is reported.
A monomer functionalized with azide and an internal alkyne crystallized as an unreactive …

Anisotropic thermal expansion as the source of macroscopic and molecular scale motion in phosphorescent amphidynamic crystals

M Jin, S Yamamoto, T Seki, H Ito… - Angewandte Chemie …, 2019 - Wiley Online Library
Herein we report a crystalline molecular rotor with rotationally modulated triplet emission
that displays macroscopic dynamics in the form of crystal moving and/or jumping, also …

Modulation of Rotational Dynamics in Halogen-Bonded Cocrystalline Solids

SS Gunaga, DL Bryce - Journal of the American Chemical Society, 2023 - ACS Publications
Dynamic processes are responsible for the functionality of a range of materials,
biomolecules, and catalysts. We report a detailed systematic study of the modulation of …