Combustion chemistry in the twenty-first century: Developing theory-informed chemical kinetics models

JA Miller, R Sivaramakrishnan, Y Tao… - Progress in Energy and …, 2021 - Elsevier
Over the last 20 to 25 years theoretical chemistry (particularly theoretical chemical kinetics)
has played an increasingly important role in developing chemical kinetics models for …

From theoretical reaction dynamics to chemical modeling of combustion

SJ Klippenstein - Proceedings of the Combustion Institute, 2017 - Elsevier
The chemical modeling of combustion treats the chemical conversion of hundreds of species
through thousands of reactions. Recent advances in theoretical methodologies and …

High-pressure oxidation of methane

H Hashemi, JM Christensen, S Gersen, H Levinsky… - Combustion and …, 2016 - Elsevier
Methane oxidation at high pressures and intermediate temperatures was investigated in a
laminar flow reactor and in a rapid compression machine (RCM). The flow-reactor …

[HTML][HTML] Comparison of methane combustion mechanisms using laminar burning velocity measurements

P Zhang, IG Zsély, M Papp, T Nagy, T Turányi - Combustion and Flame, 2022 - Elsevier
Large amount of experimental data for laminar burning velocity (LBV) measurements of
methane (+ H 2/CO)− oxygen− diluent mixtures (5500 data points in 646 datasets) covering …

Uncertainty quantification of a newly optimized methanol and formaldehyde combustion mechanism

C Olm, T Varga, É Valkó, HJ Curran, T Turányi - Combustion and Flame, 2017 - Elsevier
A detailed reaction mechanism for methanol combustion that is capable of describing
ignition, flame propagation and species concentration profiles with high accuracy has been …

High-pressure oxidation of ethane

H Hashemi, JG Jacobsen, CT Rasmussen… - Combustion and …, 2017 - Elsevier
Ethane oxidation at intermediate temperatures and high pressures has been investigated in
both a laminar flow reactor and a rapid compression machine (RCM). The flow-reactor …

[HTML][HTML] Experimental and kinetic modeling study of NO formation in premixed CH4+ O2+ N2 flames

X Han, ML Lavadera, C Brackmann, Z Wang, Y He… - Combustion and …, 2021 - Elsevier
The nitric oxide (NO) formation in methane (CH 4) flames has been widely investigated, with
quite a few kinetic mechanisms available in the literature. However, studies have shown that …

Experimental and Kinetic Modeling Study of C2H2 Oxidation at High Pressure

J Gimenez‐Lopez, CT Rasmussen… - … Journal of Chemical …, 2016 - Wiley Online Library
ABSTRACT A detailed chemical kinetic model for oxidation of acetylene at intermediate
temperatures and high pressure has been developed and evaluated experimentally. The …

Detailed kinetic modeling of dimethoxymethane. Part I: Ab initio thermochemistry and kinetics predictions for key reactions

WA Kopp, LC Kröger, M Döntgen, S Jacobs… - Combustion and …, 2018 - Elsevier
Despite the great interest in oxygenated methyl ethers as diesel fuel additives and as fuels
themselves, the influence of their methylenedioxy group (s)(O–CH 2–O) has never been …

Non-Boltzmann effects in chain branching and pathway branching for diethyl ether oxidation

CR Mulvihill, AD Danilack, CF Goldsmith… - Energy & …, 2021 - ACS Publications
Low-temperature (LT) engine applications have several potential benefits, including
reduced emissions and increased efficiency. Attaining these benefits requires accurate …