A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …

Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Transition metal (TM) catalyzed cross-coupling reactions are the utmost versatile and
reliable methods for the production of many industrially important fine chemicals. The …

The coupling of aryl or vinyl halides with terminal acetylenes catalysed by palladium and
other transition metals, commonly termed as Sonogashira cross-coupling reaction, is one of …

1. INTRODUCTION Bulk gold, being the most stable among all metals, was for many years
considered as an inert catalyst. However, gold particles with size on the scale of nanometers …

Gold has been used for coinage, jewelry, and other arts for thousands of years due to its
stability in air. Catalytic researchers were long misled by this common sense until the …

Although already established as distinct areas of practice by chemists by the late 19th
century, a formal distinction between homogeneous and other types of catalysis was only …

Transition‐metal‐catalyzed cross‐coupling reactions are central to many organic synthesis
methodologies. Traditionally, Pd, Ni, Cu, and Fe catalysts are used to promote these …

This Review showcases the ability of bi‐and tridentate ligands to stabilize gold in high
oxidation states through the formation of mono‐and biscyclometalated gold (III) complexes …