The development of carbamoyl chlorides as synthons for various amide-containing
molecules and heterocycles has been summarized and discussed in this review article …

Borylation has become a powerful method to synthesize organoboranes as versatile
building blocks in organic synthesis, medicinal chemistry, and materials science. Copper …

An approach for the copper-catalyzed synthesis of enantioenriched amides bearing an α-
stereogenic center is disclosed. This method involves the addition of an allyl copper species …

Nitrogen-based heterocycles have aroused widespread interest due to their reoccurrence in
many pharmaceuticals. Amongst these motifs, the enantioenriched lactams are the …

A copper catalyzed borocarbonylation of BCPs via proximal C–C bond cleavage for the
synthesis of γ-boryl-γ, δ-unsaturated carbonyl compounds has been developed. Using …

A visible-light photoredox-catalyzed reductive α-aminomethyl carboxylation of styrenes with
sodium glycinates and CO2 has been developed to synthesize a series of α, α-disubstituted …

Comprehensive Summary Transition metal‐catalyzed difunctionalization of tethered alkene
has emerged as a prevailing tool for the expedient construction of synthetically valuable …

Herein we report a nickel-catalyzed asymmetric reductive dicarbamoylation of alkenes, in
which tethered carbamoyl chlorides and isocyanates serve as distinct electrophilic …

We report an enantioselective copper-catalyzed Kinugasa/aldol domino reaction. This
strategy enables access to a range of spirocyclic β-lactam pyrrolidinones in a …

This review summarizes recent developments and synthetic applications of nonprecious
metal catalysis (NPMC) published between July and October 2020. It is the next installment …