Tetracyanobutadiene Bridged Push‐Pull Chromophores: Development of New Generation Optoelectronic Materials
This review describes the design strategies used for the synthesis of various
tetracyanobutadiene bridged donor‐acceptor molecular architectures by a click type [2+ 2] …
tetracyanobutadiene bridged donor‐acceptor molecular architectures by a click type [2+ 2] …
Photoinduced Charge Separation Prompted Intervalence Charge Transfer in a Bis (thienyl) diketopyrrolopyrrole Bridged Donor‐TCBD Push‐Pull System
Intervalence charge transfer (IVCT), a phenomenon observed in molecular systems
comprised of two redox centers differing in oxidation states by one unit, is reported in a …
comprised of two redox centers differing in oxidation states by one unit, is reported in a …
Superior Photophysical and Photosensitizing Properties of Nanoaggregates of Weakly Emissive Dyes for Use in Bioimaging and Photodynamic Therapy
The development of luminescent dyes based on 1, 1, 4, 4-tetracyanobuta-1, 3-dienes
(TCBDs) is an active research area, and a quantum yield (ΦF) of 7.8% has been achieved …
(TCBDs) is an active research area, and a quantum yield (ΦF) of 7.8% has been achieved …
Symmetrically Functionalized Copper and Silver Corrole‐Bis‐Tetracyanobutadiene Push‐Pull Conjugates: Efficient Population of Triplet States via Charge Transfer
Copper and silver tritolylcorroles (TTC) are symmetrically functionalized to carry two
tetracyanobutadiene (TCBD) entities via [2+ 2] cycloaddition‐retroeletrocyclization reaction …
tetracyanobutadiene (TCBD) entities via [2+ 2] cycloaddition‐retroeletrocyclization reaction …
Near‐IR Intramolecular Charge Transfer in Strongly Interacting Diphenothiazene‐TCBD and Diphenothiazene‐DCNQ Push‐Pull Triads
Three types of phenothiazines dimers (PTZ‐PTZ, 1–3), covalently linked with one or two
acetylene linkers, were synthesized by copper‐mediated Eglinton and Pd‐catalyzed …
acetylene linkers, were synthesized by copper‐mediated Eglinton and Pd‐catalyzed …
Does Location of BF2-Chelated Dipyrromethene (BODIPY) Ring Functionalization Affect Spectral and Electron Transfer Properties? Studies on α-, β-, and Meso …
The effect of positioning an electron donor, ferrocene (Fc), and a charge transfer complex, Fc–
tetracyanobutadine (TCBD), at different locations of the BF2-chelated dipyrromethene …
tetracyanobutadine (TCBD), at different locations of the BF2-chelated dipyrromethene …
Photoinduced Cascading Charge Transfer in Perylene Bisimide-Based Triads
H Loong, J Zhou, N Jiang, Y Feng, G Xie… - The Journal of …, 2022 - ACS Publications
We synthesize three perylene bisimide-based triads with donor–acceptor–acceptor (D∼ A1–
A2) architectures, in which the distance between D and A1 is varied to study its influence on …
A2) architectures, in which the distance between D and A1 is varied to study its influence on …
Accelerated Intramolecular Charge Transfer in Tetracyanobutadiene-and Expanded Tetracyanobutadiene-Incorporated Asymmetric Triphenylamine–Quinoxaline …
The excited-state properties of an asymmetric triphenylamine–quinoxaline push–pull system
wherein triphenylamine and quinoxaline take up the roles of an electron donor and …
wherein triphenylamine and quinoxaline take up the roles of an electron donor and …
Excitation Wavelength-Dependent Charge Stabilization in Highly Interacting Phenothiazine Sulfone-Derived Donor–Acceptor Constructs
Prolonging the lifetime of charge-separated states (CSS) is of paramount importance in
artificial photosynthetic donor–acceptor (DA) constructs to build the next generation of light …
artificial photosynthetic donor–acceptor (DA) constructs to build the next generation of light …
Near-IR absorbing 1, 1, 4, 4-tetracyanobutadiene-functionalized phenothiazine sulfones
Triphenylamine (TPA) substituted π-conjugated chromophores TPA1–TPA5 were designed
and synthesized via Pd-catalysed Sonogashira cross-coupling followed by [2+ 2] …
and synthesized via Pd-catalysed Sonogashira cross-coupling followed by [2+ 2] …