Recent developments in the chemistry of cubic polyhedral oligosilsesquioxanes
DB Cordes, PD Lickiss, F Rataboul - Chemical reviews, 2010 - ACS Publications
The study of the chemistry of compounds containing Si-O bonds has for many years been
dominated by both silica and minerals for which the formula unit SiO2 is important, or by the …
dominated by both silica and minerals for which the formula unit SiO2 is important, or by the …
Catalytic silylation of O–nucleophiles via Si–H or Si–C bond cleavage: A route to silyl ethers, silanols and siloxanes
K Kuciński, H Stachowiak-Dłużyńska… - Coordination Chemistry …, 2022 - Elsevier
The silylation of various O–nucleophiles (eg, alcohols, silanols, etc.) leads to desired and
commonly used compounds such as silyl ethers (alkoxysilanes) or siloxanes. The most …
commonly used compounds such as silyl ethers (alkoxysilanes) or siloxanes. The most …
A fusion of molecular imprinting technology and siloxane chemistry: A way to advanced hybrid nanomaterials
M Woźnica, M Sobiech, P Luliński - Nanomaterials, 2023 - mdpi.com
Molecular imprinting technology is a well-known strategy to synthesize materials with a
predetermined specificity. For fifty years, the “classical” approach assumed the creation of …
predetermined specificity. For fifty years, the “classical” approach assumed the creation of …
Cubic silsesquioxanes for use in solution processable organic light emitting diodes (OLED)
Commercial products using organic light emitting diode (OLED) display technology have
begun to appear in cell phones, mp3 players and even televisions. One key area that has …
begun to appear in cell phones, mp3 players and even televisions. One key area that has …
Catalytic formation of silicon–heteroatom (N, P, O, S) bonds
K Kuciński, G Hreczycho - ChemCatChem, 2017 - Wiley Online Library
Silicon and its compounds with other heteroatoms have received considerable attention,
particularly because of their applicative ability. Silicon forms a large number of compounds …
particularly because of their applicative ability. Silicon forms a large number of compounds …
Silanol-based pincer pt (II) complexes: Synthesis, structure, and unusual reactivity
EE Korshin, G Leitus, LJW Shimon… - Inorganic …, 2008 - ACS Publications
Aiming at the generation of a silanone intramolecularly bound to platinum, we prepared
pincer-type PSiP silanol Pt (II) complexes. While a stable silanone complex was not isolated …
pincer-type PSiP silanol Pt (II) complexes. While a stable silanone complex was not isolated …
Hydrolysis of polydimethylsiloxane fluids in controlled aqueous solutions
Accelerated degradation tests were performed on polydimethylsiloxane (PDMS) fluids in
aqueous solutions and in extreme chemical conditions (pH 2–4 and 9–12). Results …
aqueous solutions and in extreme chemical conditions (pH 2–4 and 9–12). Results …
Thermally insulating, thermal shock resistant calcium aluminate phosphate cement composites for reservoir thermal energy storage
T Sugama, T Pyatina - Materials, 2022 - mdpi.com
This paper presents the use of hydrophobic silica aerogel (HSA) and hydrophilic fly ash
cenosphere (FCS) aggregates for improvements in the thermal insulating and mechanical …
cenosphere (FCS) aggregates for improvements in the thermal insulating and mechanical …
Cobalt-catalyzed selective synthesis of disiloxanes and hydrodisiloxanes
S Pattanaik, C Gunanathan - ACS Catalysis, 2019 - ACS Publications
Selective syntheses of symmetrical siloxanes and cyclotetrasiloxanes are attained from
reactions of silanes and dihydrosilanes, respectively, with water, and the reactions are …
reactions of silanes and dihydrosilanes, respectively, with water, and the reactions are …
Synthesis and Reactivity of the First Isolated Hydrogen‐Bridged Silanol–Silanolate Anions
RF Weitkamp, B Neumann… - Angewandte Chemie …, 2020 - Wiley Online Library
We report on the first examples of isolated silanol–silanolate anions, obtained by utilizing
weakly coordinating phosphazenium counterions. The silanolate anions were synthesized …
weakly coordinating phosphazenium counterions. The silanolate anions were synthesized …