Recent developments in the chemistry of cubic polyhedral oligosilsesquioxanes

DB Cordes, PD Lickiss, F Rataboul - Chemical reviews, 2010 - ACS Publications
The study of the chemistry of compounds containing Si-O bonds has for many years been
dominated by both silica and minerals for which the formula unit SiO2 is important, or by the …

Catalytic silylation of O–nucleophiles via Si–H or Si–C bond cleavage: A route to silyl ethers, silanols and siloxanes

K Kuciński, H Stachowiak-Dłużyńska… - Coordination Chemistry …, 2022 - Elsevier
The silylation of various O–nucleophiles (eg, alcohols, silanols, etc.) leads to desired and
commonly used compounds such as silyl ethers (alkoxysilanes) or siloxanes. The most …

A fusion of molecular imprinting technology and siloxane chemistry: A way to advanced hybrid nanomaterials

M Woźnica, M Sobiech, P Luliński - Nanomaterials, 2023 - mdpi.com
Molecular imprinting technology is a well-known strategy to synthesize materials with a
predetermined specificity. For fifty years, the “classical” approach assumed the creation of …

Cubic silsesquioxanes for use in solution processable organic light emitting diodes (OLED)

KL Chan, P Sonar, A Sellinger - Journal of Materials Chemistry, 2009 - pubs.rsc.org
Commercial products using organic light emitting diode (OLED) display technology have
begun to appear in cell phones, mp3 players and even televisions. One key area that has …

Catalytic formation of silicon–heteroatom (N, P, O, S) bonds

K Kuciński, G Hreczycho - ChemCatChem, 2017 - Wiley Online Library
Silicon and its compounds with other heteroatoms have received considerable attention,
particularly because of their applicative ability. Silicon forms a large number of compounds …

Silanol-based pincer pt (II) complexes: Synthesis, structure, and unusual reactivity

EE Korshin, G Leitus, LJW Shimon… - Inorganic …, 2008 - ACS Publications
Aiming at the generation of a silanone intramolecularly bound to platinum, we prepared
pincer-type PSiP silanol Pt (II) complexes. While a stable silanone complex was not isolated …

Hydrolysis of polydimethylsiloxane fluids in controlled aqueous solutions

G Ducom, B Laubie, A Ohannessian… - Water science and …, 2013 - iwaponline.com
Accelerated degradation tests were performed on polydimethylsiloxane (PDMS) fluids in
aqueous solutions and in extreme chemical conditions (pH 2–4 and 9–12). Results …

Thermally insulating, thermal shock resistant calcium aluminate phosphate cement composites for reservoir thermal energy storage

T Sugama, T Pyatina - Materials, 2022 - mdpi.com
This paper presents the use of hydrophobic silica aerogel (HSA) and hydrophilic fly ash
cenosphere (FCS) aggregates for improvements in the thermal insulating and mechanical …

Cobalt-catalyzed selective synthesis of disiloxanes and hydrodisiloxanes

S Pattanaik, C Gunanathan - ACS Catalysis, 2019 - ACS Publications
Selective syntheses of symmetrical siloxanes and cyclotetrasiloxanes are attained from
reactions of silanes and dihydrosilanes, respectively, with water, and the reactions are …

Synthesis and Reactivity of the First Isolated Hydrogen‐Bridged Silanol–Silanolate Anions

RF Weitkamp, B Neumann… - Angewandte Chemie …, 2020 - Wiley Online Library
We report on the first examples of isolated silanol–silanolate anions, obtained by utilizing
weakly coordinating phosphazenium counterions. The silanolate anions were synthesized …