Large easy-axis magnetic anisotropy in a series of trigonal prismatic mononuclear cobalt (II) complexes with zero-field hidden single-molecule magnet behaviour: the …
A Landart-Gereka, MM Quesada-Moreno… - Inorganic Chemistry …, 2022 - pubs.rsc.org
The complexes [Co (L)] X· S (X= CoCl42−, S= CH3CN (1); X= ZnCl42−, S= CH3OH (2)),[Co
(L)] X2· S (X= ClO4−, S= 2CH3OH (3) and X= BF4−(4)) and [Co (L)(NCS) 2](5), where L= the …
(L)] X2· S (X= ClO4−, S= 2CH3OH (3) and X= BF4−(4)) and [Co (L)(NCS) 2](5), where L= the …
Cobalt (II) complexes as single-ion magnets
This book chapter is mainly devoted to the recent findings about the cobalt (II) single-ion
magnets (SIMs). Influence of various coordination numbers (from 2 to 8) around Co (II) in …
magnets (SIMs). Influence of various coordination numbers (from 2 to 8) around Co (II) in …
Smart ligands for efficient 3d-, 4d-and 5d-metal single-molecule magnets and single-ion magnets
PS Perlepe, D Maniaki, E Pilichos, E Katsoulakou… - Inorganics, 2020 - mdpi.com
There has been a renaissance in the interdisciplinary field of Molecular Magnetism since~
2000, due to the discovery of the impressive properties and potential applications of d-and f …
2000, due to the discovery of the impressive properties and potential applications of d-and f …
19F PARASHIFT Probes for Magnetic Resonance Detection of H2O2 and Peroxidase Activity
Elevated levels of reactive oxygen species and peroxidase expression are often associated
with inflammation and inflammatory diseases. We developed two novel Co (II) complexes …
with inflammation and inflammatory diseases. We developed two novel Co (II) complexes …
Trigonal prismatic cobalt (II) single-ion magnets: Manipulating the magnetic relaxation through symmetry control
Two mononuclear trigonal prismatic Co (II) complexes [Co (tppm*)][BPh4] 2 (1) and [Co
(hpy)][BPh4] 2· 3CH2Cl2 (2)(tppm*= 6, 6′, 6 ″-(methoxymethanetriyl) tris (2-(1 H-pyrazol-1 …
(hpy)][BPh4] 2· 3CH2Cl2 (2)(tppm*= 6, 6′, 6 ″-(methoxymethanetriyl) tris (2-(1 H-pyrazol-1 …
Structure-property correlation in stabilizing axial magnetic anisotropy in octahedral Co (II) complexes
Stabilizing an easy axis of magnetization in an octahedral Co (II) complex is an extremely
challenging task, which is evident from reports that more than 90% possess easy-plane …
challenging task, which is evident from reports that more than 90% possess easy-plane …
Synthesis, X-ray structure and magnetic properties of the apically functionalized monocapped cobalt (ii) tris-pyridineoximates possessing SMM behaviour
AS Belov, SA Belova, NN Efimov, VV Zlobina… - Dalton …, 2023 - pubs.rsc.org
The title cobalt (II) pseudoclathrochelate complexes possess an intermediate trigonal
prismatic–trigonal antiprismatic geometry. As follows from PPMS data, they exhibit an SMM …
prismatic–trigonal antiprismatic geometry. As follows from PPMS data, they exhibit an SMM …
A trigonal prismatic cobalt (II) complex as a single molecule magnet with a reduced contribution from quantum tunneling
AA Pavlov, DY Aleshin, SA Savkina, AS Belov… - …, 2019 - Wiley Online Library
Herein, we report a new trigonal prismatic cobalt (II) complex that behaves as a single
molecule magnet. The obtained zero‐field splitting, which is also directly accessed by THz …
molecule magnet. The obtained zero‐field splitting, which is also directly accessed by THz …
57 Fe Mössbauer and DFT study of the electronic and spatial structures of the iron (ii)(pseudo) clathrochelates: the effect of ligand field strength
DV Balatskiy, AS Chuprin, SV Dudkin… - Physical Chemistry …, 2023 - pubs.rsc.org
Combined experimental 57Fe Mössbauer and theoretical DFT study of a series of iron (II)-
centered (pseudo) macrobicyclic analogs and homologs was performed. The field strength …
centered (pseudo) macrobicyclic analogs and homologs was performed. The field strength …
In Situ NMR Search for Spin-Crossover in Heteroleptic Cobalt(II) Complexes
Y Pankratova, D Aleshin, I Nikovskiy… - Inorganic …, 2020 - ACS Publications
Here we report the first successful attempt to identify spin-crossover compounds in solutions
of metal complexes produced by mixing different ligands and an appropriate metal salt by …
of metal complexes produced by mixing different ligands and an appropriate metal salt by …