Advances in the Catalytic Hydrogenation and Properties of Unsaturated Polymers

JY Yan, GP Cao - Macromolecules, 2023 - ACS Publications
Polymer reaction and performance improvement are one of the important contents in the
field of polymer materials science and engineering, in which polymer catalytic …

Pore-size dependent catalytic activity of supported Pd catalysts for selective hydrogenation of nitrile butadiene rubber

S Wang, Y Wang, X Wu, C Hu, H Zhang, Q Cui… - Chemical Engineering …, 2023 - Elsevier
Pore diffusion effect plays a crucial role in heterogeneous hydrogenation of unsaturated
polymers. However, how large pore size can eliminate the pore diffusion limitation remains a …

Mechanism of NCNTs Growth on Foamed Nickel and Thus-Prepared PS Hydrogenation High-Performance Carrier NCNTs@ FN

JY Yan, CY Cao, GP Cao, SF Pan, H Lv, AMM Saeed - Langmuir, 2024 - ACS Publications
Traditional heterogeneous catalysts are affected in the catalytic hydrogenation of PS by the
scale effect, viscosity effect, adhesion effect, and conformational effect, resulting in poor …

Mechanism and Kinetics of Polystyrene Hydrogenation Catalyzed by a Monolithic Pd-NCNTs@ FN Catalyst

JY Yan, GP Cao, CY Cao, P Gao… - Industrial & …, 2024 - ACS Publications
This work investigated the loading of active metals on monolithic carrier NCNTs@ FN
through simulation and characterization and found that the active metal (Pd) had a stronger …

Palladium supported on carbon nanotube modified nickel foam as a structured catalyst for polystyrene hydrogenation

M Feng, ZH Luo, RQ Chen, S Yi, H Lu, GP Cao… - Applied Catalysis A …, 2019 - Elsevier
A structured support of carbon nanotubes modified nickel foam (CNTs@ NF) was
synthesized through a facile method of chemical vapor deposition. The entangled CNTs …

Palladium supported on carbon nanotubes decorated nickel foam as the catalytic stirrer in heterogeneous hydrogenation of polystyrene

M Feng, ZH Luo, S Yi, H Lu, C Lu, CY Li… - Industrial & …, 2018 - ACS Publications
Carbon nanotubes supported palladium (Pd/CNTs) catalyst displayed excellent activity
toward hydrogenation of polystyrene (PS) to produce polycyclohexylethylene (PCHE) with …

A new α-CBC polymer with elevated heat-resistance prepared via catalytic hydrogenation of α-methylstyrene-butadiene-styrene terpolymer over NixPd/NCNT@MFN …

CY Cao, SK Qian, GP Cao, JY Yan, P Gao… - Journal of Polymer …, 2024 - Springer
Elevating the heat resistance of the highly transparent cyclic block copolymer (CBC) is of
great significance for the synthesis of high-performance polymers. In this study, a novel …

Tunable growth of carbon nanotubes forests on nickel foam as structured support for palladium catalyst toward polystyrene hydrogenation

M Feng, ZH Luo, GP Cao, H Lu - Journal of the Taiwan Institute of Chemical …, 2019 - Elsevier
Heterogeneous catalytic hydrogenation of polystyrene (PS) over classical porous catalysts
to polycyclohexylethylene (PCHE) with added commercial values is severely limited by pore …

High catalytic efficiency of Pd nanoparticles immobilized on TiO2 nanorods‐coated ceramic membranes

S Zhang, H Jiang, Y Liu, R Chen - The Canadian Journal of …, 2017 - Wiley Online Library
In this work, we designed and constructed an efficient and reusable membrane catalyst by
loading palladium (Pd) nanoparticles on TiO2 nanorods (NRs)‐coated ceramic membrane …

Preparation of Al2O3 and MgAl2O4-based samples with tailored macroporous structures

GT Araújo, TS Brito, DF Souza, AMA Silva… - Ceramics …, 2018 - Elsevier
In this work we successfully obtained freeze-cast alumina (Al 2 O 3) and magnesium
aluminate spinel (MgAl 2 O 4) samples. Camphene was used as the freezing vehicle in this …