Enantioselective Synthesis of Atropisomers via Vinylidene ortho-Quinone Methides (VQMs)
W Qin, Y Liu, H Yan - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Atropisomers, arising from conformational restriction, are inherently chiral due
to the intersecting dissymmetric planes. Since there are numerous applications of …
to the intersecting dissymmetric planes. Since there are numerous applications of …
Biologically active secondary metabolites from the fungi
Many Fungi have a well-developed secondary metabolism. The diversity of fungal species
and the diversification of biosynthetic gene clusters underscores a nearly limitless potential …
and the diversification of biosynthetic gene clusters underscores a nearly limitless potential …
Iterative polyketide biosynthesis by modular polyketide synthases in bacteria
Modular polyketide synthases (type I PKSs) in bacteria are responsible for synthesizing a
significant percentage of bioactive natural products. This group of synthases has a …
significant percentage of bioactive natural products. This group of synthases has a …
Design of Ru (II)-NHC-diamine precatalysts directed by ligand cooperation: applications and mechanistic investigations for asymmetric hydrogenation
W Li, T Wagener, L Hellmann, CG Daniliuc… - Journal of the …, 2020 - ACS Publications
A modular synthesis of Ru (II)-NHC-diamine complexes from readily available chiral N-
heterocyclic carbenes (NHCs) and chiral diamines is disclosed for the first time. The well …
heterocyclic carbenes (NHCs) and chiral diamines is disclosed for the first time. The well …
Fungal volatiles–a survey from edible mushrooms to moulds
JS Dickschat - Natural Product Reports, 2017 - pubs.rsc.org
Covering: up to January 2017 This review gives a comprehensive overview of the
production of fungal volatiles, including the history of the discovery of the first compounds …
production of fungal volatiles, including the history of the discovery of the first compounds …
Regiospecific ortho‐C−H Allylation of Benzoic Acids
AS Trita, A Biafora, M Pichette Drapeau… - Angewandte Chemie …, 2018 - Wiley Online Library
A carboxylate‐directed ortho‐C− H functionalization has been developed and it allows the
regiospecific introduction of allyl residues to benzoic acids. In the presence of a [Ru (p …
regiospecific introduction of allyl residues to benzoic acids. In the presence of a [Ru (p …
Melleins—Intriguing natural compounds
Melleins are 3, 4-dihydroisocoumarins mainly produced by fungi, but also by plants, insects
and bacteria. These specialized metabolites play important roles in the life cycles of the …
and bacteria. These specialized metabolites play important roles in the life cycles of the …
Recent advances in combinatorial biosynthesis for drug discovery
Because of extraordinary structural diversity and broad biological activities, natural products
have played a significant role in drug discovery. These therapeutically important secondary …
have played a significant role in drug discovery. These therapeutically important secondary …
Organocatalytic Aerobic Oxidation of Benzylic sp3 C–H Bonds of Ethers and Alkylarenes Promoted by a Recyclable TEMPO Catalyst
An entirely metal-free catalyst system consisting of an easily prepared recyclable new
TEMPO derived sulfonic salt catalyst, and mineral acids (NaNO2 and HCl) has been …
TEMPO derived sulfonic salt catalyst, and mineral acids (NaNO2 and HCl) has been …
The scent of bacteria: headspace analysis for the discovery of natural products
CA Citron, P Rabe, JS Dickschat - Journal of natural products, 2012 - ACS Publications
Volatile compounds released by 50 bacterial strains, 45 of them actinobacteria in addition to
three chloroflexi and two myxobacteria, have been collected by use of a closed-loop …
three chloroflexi and two myxobacteria, have been collected by use of a closed-loop …