Knotting matters: orderly molecular entanglements
Entangling strands in a well-ordered manner can produce useful effects, from shoelaces and
fishing nets to brown paper packages tied up with strings. At the nanoscale, non-crystalline …
fishing nets to brown paper packages tied up with strings. At the nanoscale, non-crystalline …
Coordination-directed construction of molecular links
Since the emergence of the concept of chemical topology, interlocked molecular assemblies
have graduated from academic curiosities and poorly defined species to become synthetic …
have graduated from academic curiosities and poorly defined species to become synthetic …
The rise and promise of molecular nanotopology
Molecular nanotopology—a term we coined recently—is a rapidly developing field of
research that is emerging out of the confluence of chemical topology with the mechanical …
research that is emerging out of the confluence of chemical topology with the mechanical …
A Self‐Assembled Cage Binding Iodide Anions over Other Halide Ions in Water
Y Wu, C Zhang, S Fang, D Zhu, Y Chen… - Angewandte …, 2022 - Wiley Online Library
A triangular‐prism shaped cage was self‐assembled by the formation of a dynamic covalent
bond, namely a hydrazone, in acidic aqueous solution. The hexacationic host bears a …
bond, namely a hydrazone, in acidic aqueous solution. The hexacationic host bears a …
Self‐Assembly in Water with N‐Substituted Imines
Imine synthesis has enjoyed a long history as the dynamic covalent reaction of choice for the
construction of purely covalent molecular architectures. In organic solvents, the formation of …
construction of purely covalent molecular architectures. In organic solvents, the formation of …
Iminopyrrole‐Based Self‐Assembly: A Route to Intrinsically Flexible Molecular Links and Knots
A Sarwa, A Białońska, M Sobieraj… - Angewandte …, 2024 - Wiley Online Library
Abstract The use of 2, 5‐diformylpyrrole in self‐assembly reactions with diamines and Zn
(II)/Cd (II) salts allowed the preparation of [2] catenane, trefoil knot, and Borromean rings …
(II)/Cd (II) salts allowed the preparation of [2] catenane, trefoil knot, and Borromean rings …
Cross dehydrogenative C–O coupling catalysed by a catenane-coordinated copper (I)
L Zhu, J Li, J Yang, HY Au-Yeung - Chemical Science, 2020 - pubs.rsc.org
Catalytic activity of copper (I) complexes supported by phenanthroline-containing catenane
ligands towards a new C (sp3)–O dehydrogenative cross-coupling of phenols and …
ligands towards a new C (sp3)–O dehydrogenative cross-coupling of phenols and …
Macrocycle dynamics in a branched [8] catenane controlled by three different stimuli in three different regions
A branched [8] catenane from an efficient one‐pot synthesis (72% HPLC yield, 59% isolated
yield) featuring the simultaneous use of three kinds of templates and cucurbit [6] uril …
yield) featuring the simultaneous use of three kinds of templates and cucurbit [6] uril …
Effects of turn-structure on folding and entanglement in artificial molecular overhand knots
The length and constitution of spacers linking three 2, 6-pyridinedicarboxamide units in a
molecular strand influence the tightness of the resulting overhand (open-trefoil) knot that the …
molecular strand influence the tightness of the resulting overhand (open-trefoil) knot that the …
Ultramacrocyclization in water via external templation
Q Chen, Y Lei, G Wu, Q Li, Y Pan, H Li - Chemical Science, 2022 - pubs.rsc.org
Condensing a dihydrazide and each of a series of cationic bisaldehyde compounds bearing
polymethylene chains in weakly acidic water produces either a macrocycle in a [1+ 1] …
polymethylene chains in weakly acidic water produces either a macrocycle in a [1+ 1] …