Recent advances in transition-metal-catalyzed carbene insertion to C–H bonds
Y He, Z Huang, K Wu, J Ma, YG Zhou… - Chemical Society Reviews, 2022 - pubs.rsc.org
C–H functionalization has been emerging as a powerful method to establish carbon–carbon
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …
Bidentate directing groups: an efficient tool in C–H bond functionalization chemistry for the expedient construction of C–C bonds
S Rej, Y Ano, N Chatani - Chemical reviews, 2020 - ACS Publications
During the past decades, synthetic organic chemistry discovered that directing group
assisted C–H activation is a key tool for the expedient and siteselective construction of C–C …
assisted C–H activation is a key tool for the expedient and siteselective construction of C–C …
3d transition metals for C–H activation
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …
notable applications to material sciences, crop protection, drug discovery, and …
[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry
C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …
Recent Advances in Mn, Fe, Co, and Ni-Catalyzed Organic Reactions
This paper reviewed the recent research progress of organic reactions catalyzed by four
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …
Rhodium‐Catalyzed C(sp2)‐ or C(sp3)−H Bond Functionalization Assisted by Removable Directing Groups
S Rej, N Chatani - Angewandte Chemie International Edition, 2019 - Wiley Online Library
In recent years, transition‐metal‐catalyzed C− H activation has become a key strategy in the
field of organic synthesis. Rhodium complexes are widely used as catalysts in a variety of …
field of organic synthesis. Rhodium complexes are widely used as catalysts in a variety of …
Cobalt-catalyzed C–H activation
M Moselage, J Li, L Ackermann - ACS Catalysis, 2016 - ACS Publications
Catalytic C–H activation has emerged as a powerful tool for sustainable syntheses. In the
recent years, notable success was achieved with the development of cobalt-catalyzed C–H …
recent years, notable success was achieved with the development of cobalt-catalyzed C–H …
Chemodivergent reactions
IP Beletskaya, C Nájera, M Yus - Chemical Society Reviews, 2020 - pubs.rsc.org
An important strategy for the efficient generation of diversity in molecular structures is the
utilization of common starting materials in chemodivergent transformations. The most …
utilization of common starting materials in chemodivergent transformations. The most …
Electrochemical C− H/N− H activation by water‐tolerant cobalt catalysis at room temperature
Abstract Electrochemistry enabled C− H/N− H functionalizations at room temperature by
external oxidant‐free cobalt catalysis. Thus, the sustainable cobalt electrocatalysis manifold …
external oxidant‐free cobalt catalysis. Thus, the sustainable cobalt electrocatalysis manifold …
Electroremovable traceless hydrazides for cobalt-catalyzed electro-oxidative C–H/N–H activation with internal alkynes
R Mei, N Sauermann, JCA Oliveira… - Journal of the American …, 2018 - ACS Publications
Electrochemical oxidative C–H/N–H activations have been accomplished with a versatile
cobalt catalyst in terms of [4+ 2] annulations of internal alkynes. The electro-oxidative C–H …
cobalt catalyst in terms of [4+ 2] annulations of internal alkynes. The electro-oxidative C–H …