3d transition metals for C–H activation
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …
notable applications to material sciences, crop protection, drug discovery, and …
Methodologies and strategies for selective borylation of C–Het and C–C bonds
M Wang, Z Shi - Chemical Reviews, 2020 - ACS Publications
Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …
[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry
C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …
Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions
In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …
Weak-coordination in C–H bond functionalizations catalyzed by 3d metals
Transition-metal-catalyzed C–H bond functionalizations have had an enormous influence on
organic synthesis in recent times. However, the use of low-abundance 4d and 5d metals is …
organic synthesis in recent times. However, the use of low-abundance 4d and 5d metals is …
Metal-mediated and metal-catalyzed reactions under mechanochemical conditions
A Porcheddu, E Colacino, L De Luca, F Delogu - ACS Catalysis, 2020 - ACS Publications
The extraordinary impact of metal-based complexes on synthetic methods is still recognized
nowadays, and attempts are currently undertaken to further extend the use of metal-assisted …
nowadays, and attempts are currently undertaken to further extend the use of metal-assisted …
Recent advances in positional-selective alkenylations: removable guidance for twofold C–H activation
W Ma, P Gandeepan, J Li, L Ackermann - Organic Chemistry Frontiers, 2017 - pubs.rsc.org
The transition metal-catalyzed transformation of otherwise inert C–H bonds into substituted
alkenes offers a versatile tool for the synthesis of value added olefinic molecules. Recent …
alkenes offers a versatile tool for the synthesis of value added olefinic molecules. Recent …
Recent developments in ruthenium-catalyzed C–H arylation: Array of mechanistic manifolds
Functionalized biaryl-containing motifs are among the most valuable synthetic scaffolds in
organic chemistry with wide ranging commercial applications in pharmaceuticals, functional …
organic chemistry with wide ranging commercial applications in pharmaceuticals, functional …
Highly Enantioselective Catalytic Lactonization at Nonactivated Primary and Secondary γ-C–H Bonds
Chiral oxygenated aliphatic moieties are recurrent in biological and pharmaceutically
relevant molecules and constitute one of the most versatile types of functionalities for further …
relevant molecules and constitute one of the most versatile types of functionalities for further …
Controlled functionalization of o-carborane via transition metal catalyzed B–H activation
Carboranes, a class of carbon–boron molecular clusters, are often viewed as three-
dimensional analogues of benzene. They are finding increasing applications as useful …
dimensional analogues of benzene. They are finding increasing applications as useful …