3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Methodologies and strategies for selective borylation of C–Het and C–C bonds

M Wang, Z Shi - Chemical Reviews, 2020 - ACS Publications
Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …

[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions

S Rej, A Das, N Chatani - Coordination Chemistry Reviews, 2021 - Elsevier
In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

Weak-coordination in C–H bond functionalizations catalyzed by 3d metals

R Mandal, B Garai, B Sundararaju - ACS Catalysis, 2022 - ACS Publications
Transition-metal-catalyzed C–H bond functionalizations have had an enormous influence on
organic synthesis in recent times. However, the use of low-abundance 4d and 5d metals is …

Metal-mediated and metal-catalyzed reactions under mechanochemical conditions

A Porcheddu, E Colacino, L De Luca, F Delogu - ACS Catalysis, 2020 - ACS Publications
The extraordinary impact of metal-based complexes on synthetic methods is still recognized
nowadays, and attempts are currently undertaken to further extend the use of metal-assisted …

Recent advances in positional-selective alkenylations: removable guidance for twofold C–H activation

W Ma, P Gandeepan, J Li, L Ackermann - Organic Chemistry Frontiers, 2017 - pubs.rsc.org
The transition metal-catalyzed transformation of otherwise inert C–H bonds into substituted
alkenes offers a versatile tool for the synthesis of value added olefinic molecules. Recent …

Recent developments in ruthenium-catalyzed C–H arylation: Array of mechanistic manifolds

P Nareddy, F Jordan, M Szostak - ACS Catalysis, 2017 - ACS Publications
Functionalized biaryl-containing motifs are among the most valuable synthetic scaffolds in
organic chemistry with wide ranging commercial applications in pharmaceuticals, functional …

Highly Enantioselective Catalytic Lactonization at Nonactivated Primary and Secondary γ-C–H Bonds

A Call, G Capocasa, A Palone, L Vicens… - Journal of the …, 2023 - ACS Publications
Chiral oxygenated aliphatic moieties are recurrent in biological and pharmaceutically
relevant molecules and constitute one of the most versatile types of functionalities for further …

Controlled functionalization of o-carborane via transition metal catalyzed B–H activation

Y Quan, Z Xie - Chemical Society Reviews, 2019 - pubs.rsc.org
Carboranes, a class of carbon–boron molecular clusters, are often viewed as three-
dimensional analogues of benzene. They are finding increasing applications as useful …