Thermodynamic hydricity of transition metal hydrides
Transition metal hydrides play a critical role in stoichiometric and catalytic transformations.
Knowledge of free energies for cleaving metal hydride bonds enables the prediction of …
Knowledge of free energies for cleaving metal hydride bonds enables the prediction of …
Achieving efficient n-doping of conjugated polymers by molecular dopants
Conspectus Molecular doping is one of the most central propositions in the field of organic
electronics. Unlike classical inorganic semiconductors doped by atomic substitution, organic …
electronics. Unlike classical inorganic semiconductors doped by atomic substitution, organic …
Biomimetic active sites on monolayered metal–organic frameworks for artificial photosynthesis
Enzymes have evolved to catalyse challenging chemical transformations with high efficiency
and selectivity. Although a number of artificial systems have been developed to recapitulate …
and selectivity. Although a number of artificial systems have been developed to recapitulate …
Photocatalytic CO2 reduction with aminoanthraquinone organic dyes
Q Lei, H Yuan, J Du, M Ming, S Yang, Y Chen… - Nature …, 2023 - nature.com
The direct utilization of solar energy to convert CO2 into renewable chemicals remains a
challenge. One essential difficulty is the development of efficient and inexpensive light …
challenge. One essential difficulty is the development of efficient and inexpensive light …
[HTML][HTML] Sacrificial electron donor reagents for solar fuel production
Y Pellegrin, F Odobel - Comptes Rendus Chimie, 2017 - Elsevier
Although justly considered as a cumbersome component in artificial photosystems, these
simple molecules are a “necessary evil” to drive photo-induced reactions aiming at …
simple molecules are a “necessary evil” to drive photo-induced reactions aiming at …
A thermally activated and highly miscible dopant for n-type organic thermoelectrics
N-doping plays an irreplaceable role in controlling the electron concentration of organic
semiconductors thus to improve performance of organic semiconductor devices. However …
semiconductors thus to improve performance of organic semiconductor devices. However …
Promoting photocatalytic CO2 reduction with a molecular copper purpurin chromophore
H Yuan, B Cheng, J Lei, L Jiang, Z Han - Nature Communications, 2021 - nature.com
CO2 reduction through artificial photosynthesis represents a prominent strategy toward the
conversion of solar energy into fuels or useful chemical feedstocks. In such configuration …
conversion of solar energy into fuels or useful chemical feedstocks. In such configuration …
Toward High Performance n-Type Thermoelectric Materials by Rational Modification of BDPPV Backbones
Three n-type polymers BDPPV, ClBDPPV, and FBDPPV which exhibit outstanding electrical
conductivities when mixed with an n-type dopant, N-DMBI ((4-(1, 3-dimethyl-2, 3-dihydro-1 H …
conductivities when mixed with an n-type dopant, N-DMBI ((4-(1, 3-dimethyl-2, 3-dihydro-1 H …
Rapid electron transfer via dynamic coordinative interaction boosts quantum efficiency for photocatalytic CO2 reduction
The fulfillment of a high quantum efficiency for photocatalytic CO2 reduction presents a key
challenge, which can be overcome by developing strategies for dynamic attachment …
challenge, which can be overcome by developing strategies for dynamic attachment …
Proton-coupled electron transfer
DR Weinberg, CJ Gagliardi, JF Hull, CF Murphy… - Chemical …, 2012 - ACS Publications
An initial review (PCET1) on proton-coupled electron transfer (PCET) by Huynh and Meyer
appeared in Chemical Reviews in 2007.(1) This is a follow-up on the original. It was …
appeared in Chemical Reviews in 2007.(1) This is a follow-up on the original. It was …