The increasing utilization and emission of sulfur hexafluoride (SF 6) pose severe threats to
the climate and the environment, owing to its potent greenhouse gas properties. In this …

We leveraged the recent increase in synthetic accessibility of SF5Cl and Ar− SF4Cl
compounds to combine chemistry of the SF5 and SF4Ar groups with strain‐release …

Herein is described a fully regio‐and stereoselective hydroelementation reaction of SF5‐
alkynes with N, O and S‐nucleophiles and further functionalization of the corresponding Z …

This review article outlines the literature from 2022 to 2024 covering developments in SF 5
chemistry. Recent synthetic methodologies of SF 5-containing building blocks are reported …

A series of redox‐responsive ferrocenyl‐substituted boranes and boronic esters were
synthesized. Oxidation of the ferrocenyl ligand to the ferrocenium resulted in a drastic …

Herein we report a novel methodology for the ex situ generation of SF5Cl by employing 4,
4′-dipyridyl disulfide as a safe commercial reagent, obviating the need for lecture bottles …

Alkyne hydroamination is an effective approach for the production of enamines and enamine‐
containing N‐heterocycles. However, stereoselectivity control is a considerable challenge in …

The chloropentafluorosulfanylation of alkynes is a delicate but crucial operation for
accessing SF5-alkynes that serve as substrates in numerous transformations. Dolbier's …

trans-Trifluoromethyltetrafluorosulfanyl chloride (trans-CF3SF4Cl) is a unique reagent for the
incorporation of the CF3SF4 group into organic compounds. However, CF3SF4Cl was …

The synthesis of vinyl fluorides plays a crucial role in various scientific disciplines, including
pharmaceutical and materials sciences. Herein, we present a direct and stereoselective …