Functional Short-Bite Ligands: Synthesis, Coordination Chemistry, and Applications of N-Functionalized Bis(diaryl/dialkylphosphino)amine-type Ligands

C Fliedel, A Ghisolfi, P Braunstein - Chemical reviews, 2016 - ACS Publications
The aim of this review is to highlight how the diversity generated by N-substitution in the well-
known short-bite ligand bis (diphenylphosphino) amine (DPPA) allows a fine-tuning of the …

Transfer Hydrogenation from 2-propanol to Acetophenone Catalyzed by [RuCl2 (η6-arene) P](P= monophosphine) and [Rh (PP) 2] X (PP= diphosphine, X= Cl−, BF4−) …

A Mannu, A Grabulosa, S Baldino - Catalysts, 2020 - mdpi.com
The reduction of ketones through homogeneous transfer hydrogenation catalyzed by
transition metals is one of the most important routes for obtaining alcohols from carbonyl …

Catalytic applications of small bite-angle diphosphorus ligands with single-atom linkers

SM Mansell - Dalton Transactions, 2017 - pubs.rsc.org
Diphosphorus ligands connected by a single atom (R2PEPR2; E= CR2, CCR2 and NR) give
chelating ligands with very small bite-angles (natural bite-angle of 72° for dppm) as well as …

PNP Ligands in Cobalt‐Mediated Activation and Functionalization of White Phosphorus

AM Kuchkaev, AM Kuchkaev, KR Khayarov… - Angewandte …, 2022 - Wiley Online Library
Transition‐metal mediated white phosphorus activation is of high interest as an ecological
alternative to P4 chlorination pathway to the practically useful phosphorus products. Herein …

Ruthenium (II) complexes of NO ligands: Synthesis, characterization and application in transfer hydrogenation of carbonyl compounds

HS Çalık, E Ispir, Ş Karabuga, M Aslantas - Journal of Organometallic …, 2016 - Elsevier
New Schiff base ligands including azo group such as (4-((E)-(4-ethylphenyl) diazenyl)-2-((E)-
(phenylimino) methyl) phenol 2, 4-((E)-(4-ethylphenyl) diazenyl)-2-((E)-(naphthalen-1 …

Catechol-type ligand containing new modular design dioxaborinane compounds: Use in the transfer hydrogenation of various ketones

A Kilic, İH Kaya, I Ozaslan, M Aydemir… - Catalysis Communications, 2018 - Elsevier
A novel class of tricoordinate dioxaborinane compounds, which have the general formula [B
1 (L 1–5)] and [B 2 (L 1–5)], were designed and synthesized by the corresponding catechol …

Novel half‐sandwich η5‐Cp *–rhodium(III) and η5‐Cp *–ruthenium(II) complexes bearing bis(phosphino)amine ligands and their use in the transfer hydrogenation …

F Ok, M Aydemir, F Durap… - Applied Organometallic …, 2014 - Wiley Online Library
Two new half‐sandwich η5‐Cp*–rhodium (III) and η5‐Cp*–ruthenium (II) complexes have
been prepared from corresponding bis (phosphino) amine ligands, thiophene‐2‐(N, N‐bis …

The chiral boronate-catalyzed asymmetric transfer hydrogenation of various aromatic ketones to high-value alcohols: Preparation and spectroscopic studies

A Kilic, M Durgun, F Durap, M Aydemir - Journal of Organometallic …, 2019 - Elsevier
This work deals with the synthesis, spectroscopic studies and catalytic evaluation of the
novel chiral salen (L 1 H 2) and (L 2 H 2) ligands and their chiral boronate [L 1 (B 1-4)] and …

Transfer hydrogenation of ketones catalyzed by new rhodium and iridium complexes of aminophosphine containing cyclohexyl moiety and photosensing behaviors of …

K Rafikova, N Kystaubayeva, M Aydemir… - Journal of …, 2014 - Elsevier
The reaction of [Rh (μ-Cl)(cod)] 2 and Ir (η 5-C 5 Me 5)(μ-Cl) Cl] 2 with aminophosphine
ligands Cy 2 PNHCH 2–C 4 H 3 X (X: O; S) gave a range of new monodendate [Rh (Cy 2 …

Catalytic transfer hydrogenation in γ-valerolactone-based ionic liquids

A Strádi, M Molnár, P Szakál, G Dibó, D Gáspár… - RSC …, 2015 - pubs.rsc.org
The combination of transfer hydrogenation reaction with the advantages of γ-valerolactone-
based ionic liquids could result in an environmentally benign method for the reduction of …