The traditional and recent synthetic approaches to polyhedral metallasiloxanes (PHMSs) of
different types are reviewed to demonstrate that each strategy yields a PHMS with a specific …

Although tetrameric Al (I) compounds have been known for a long time, the monomeric Al (I)
compounds that are analogous to carbenes are very recent entrants in Al (I) chemistry. They …

The chemistry of silanols and related amino‐silanes is a topic of current interest in view of
their possible applications as building blocks in materials science. In particular, discrete …

Two cage copper (II) silsesquioxanes, namely, tricopper complex (PhSiO 1.5) 8 (CuO) 3
(TMEDA) 2*(MeCN) 3 Cu-1 and hexacopper complex (MeSiO 1, 5) 12 (CuO) 6 (Py) 6 …

Triesters of phosphoric acid OP (OR) 3 (R= Me, Et, n-Bu, SiMe3) react with [M (NMe2) 3] 2
(M= Al (1), Ga (2)) in nonaqueous aprotic solvents with the formation of amorphous alumino …

The reactions of LAlH2 (L= HC (CMeNAr) 2, Ar= 2, 6-iPr2C6H3)(1) with diphenylsilanediol,
phenylphosphonic acid, diphenylphosphinic acid, and pyrocatechol afford compounds with …

Reactions of a four-membered Al− N ring,[(Dipp) HNAlMe2] 2 (2; Dipp= 2, 6-
diisopropylphenyl), with the aromatic nitriles PhCN, TbpCN (Tbp= 4-tert-butylphenyl) …

A dealkylsilylation reaction between alumazene [2, 6-(i-Pr) 2C6H3NAlMe] 3 (1) and tris
(trimethylsilyl) ester of phosphoric acid (2) in a 1: 3 molar ratio provides the …

trimethyl-2, 4, 6-tris (2, 6-diisopropylphenyl) alumazene [2, 6-(i-Pr) 2 C 6 H 3 NAlMe] 3, 1, is
a benzene-like iminoalane with a planar hexagonal (Al–N) 3 core. The aluminum centers …

Keine sperrigen Substituenten sind an die Siliciumzentren der käfigartigen Titelverbindung
1 gebunden, die einfach durch Umsetzen von Methyltrichlorsilan mit Ammoniak und Natrium …