Recent advances in heterocyclic nanographenes and other polycyclic heteroaromatic compounds

A Borissov, YK Maurya, L Moshniaha… - Chemical …, 2021 - ACS Publications
This review surveys recent progress in the chemistry of polycyclic heteroaromatic molecules
with a focus on structural diversity and synthetic methodology. The article covers literature …

Heteroatom-doped nanographenes with structural precision

XY Wang, X Yao, A Narita… - Accounts of Chemical …, 2019 - ACS Publications
Conspectus Nanographenes, which are defined as nanoscale (1–100 nm) graphene
cutouts, include quasi-one-dimensional graphene nanoribbons (GNRs) and quasi-zero …

Phenalenyl radical: Smallest polycyclic odd alternant hydrocarbon present in the graphene sheet

J Ahmed, SK Mandal - Chemical Reviews, 2022 - ACS Publications
Phenalenyl, a zigzag-edged odd alternant hydrocarbon unit can be found in the graphene
nanosheet. Hückel molecular orbital calculations indicate the presence of a nonbonding …

One-shot multiple borylation toward BN-doped nanographenes

K Matsui, S Oda, K Yoshiura, K Nakajima… - Journal of the …, 2018 - ACS Publications
One-shot double, triple, and quadruple borylation reactions of triarylamines were developed
through a judicious choice of boron source and Brønsted base. With the aid of borylation …

Heteroatom‐Embedded Approach to Vinylene‐Linked Covalent Organic Frameworks with Isoelectronic Structures for Photoredox Catalysis

S Bi, Z Zhang, F Meng, D Wu, JS Chen… - Angewandte …, 2022 - Wiley Online Library
Embedding heteroatoms into the main backbones of polymeric materials has become an
efficient tool for tailoring their structures and improving their properties. However, owing to …

Multiple-boron–nitrogen (multi-BN) doped π-conjugated systems for optoelectronics

X Chen, D Tan, DT Yang - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
Boron–nitrogen-doped π-conjugated systems have been regarded as a class of organic
materials with exceptional electronic and optical properties, which makes them promising in …

A deep blue B, N-doped heptacene emitter that shows both thermally activated delayed fluorescence and delayed fluorescence by triplet–triplet annihilation

SM Suresh, E Duda, D Hall, Z Yao… - Journal of the …, 2020 - ACS Publications
An easy-to-access, near-UV-emitting linearly extended B, N-doped heptacene with high
thermal stability is designed and synthesized in good yields. This compound exhibits …

Synthetic Tailoring of graphene nanostructures with zigzag‐edged topologies: progress and perspectives

J Liu, X Feng - Angewandte Chemie International Edition, 2020 - Wiley Online Library
Experimental and theoretical investigations have revealed that the chemical and physical
properties of graphene are crucially determined by their topological structures. Therefore …

[HTML][HTML] Intramolecular (directed) electrophilic C–H borylation

SA Iqbal, J Pahl, K Yuan, MJ Ingleson - Chemical Society Reviews, 2020 - pubs.rsc.org
The intramolecular C–H borylation of (hetero) arenes and alkenes using electrophilic
boranes is a powerful transition metal free methodology for forming C–B bonds. These C–H …

[HTML][HTML] Ultrathin two-dimensional porous organic nanosheets with molecular rotors for chemical sensing

J Dong, K Zhang, X Li, Y Qian, H Zhu, D Yuan… - Nature …, 2017 - nature.com
Molecular rotors have played an important role in recent materials chemistry. Although
several studies on functional materials containing molecular rotors have been reported for …