Single‐atom catalysts in catalytic biomedicine

H Xiang, W Feng, Y Chen - Advanced Materials, 2020 - Wiley Online Library
The intrinsic deficiencies of nanoparticle‐initiated catalysis for biomedical applications
promote the fast development of alternative versatile theranostic modalities. The catalytic …

Recent progress in multienzymes co-immobilization and multienzyme system applications

S Ren, C Li, X Jiao, S Jia, Y Jiang, M Bilal… - Chemical Engineering …, 2019 - Elsevier
Enzyme catalysis has been attracting increasing interest in the past twenty years.
Nevertheless, most reports concerning enzyme catalysis have been carried out using single …

Hierarchically encapsulating enzymes with multi-shelled metal-organic frameworks for tandem biocatalytic reactions

T Man, C Xu, XY Liu, D Li, CK Tsung, H Pei… - Nature …, 2022 - nature.com
Biocatalytic transformations in living organisms, such as multi-enzyme catalytic cascades,
proceed in different cellular membrane-compartmentalized organelles with high efficiency …

Fabricating covalent organic framework capsules with commodious microenvironment for enzymes

M Li, S Qiao, Y Zheng, YH Andaloussi… - Journal of the …, 2020 - ACS Publications
Enzyme immobilization has been demonstrated to be a favorable protocol to promote
industrialization of biomacromolecules. Despite tremendous efforts to develop new …

Biocatalytic cascades operating on macromolecular scaffolds and in confined environments

M Vázquez-González, C Wang, I Willner - Nature Catalysis, 2020 - nature.com
Biocatalytic cascades guide complex, efficient and selective intracellular transformations.
These unique features originate from the spatial organization of the biocatalysts in confined …

Self assembling nanoparticle enzyme clusters provide access to substrate channeling in multienzymatic cascades

JC Breger, JN Vranish, E Oh, MH Stewart… - Nature …, 2023 - nature.com
Access to efficient enzymatic channeling is desired for improving all manner of designer
biocatalysis. We demonstrate that enzymes constituting a multistep cascade can self …

Enzyme immobilization and co-immobilization: main framework, advances and some applications

J Bié, B Sepodes, PCB Fernandes, MHL Ribeiro - Processes, 2022 - mdpi.com
Enzymes are outstanding (bio) catalysts, not solely on account of their ability to increase
reaction rates by up to several orders of magnitude but also for the high degree of substrate …

Incorporation of chiral frustrated Lewis pair into metal–organic framework with tailored microenvironment for heterogeneous enantio-and chemoselective …

Y Zhang, Y Jiang, A Nafady, Z Tang… - ACS Central …, 2023 - ACS Publications
The development of efficient heterogeneous catalysts with multiselectivity (eg, enantio-and
chemoselectivity) has long been sought after but with limited progress being made so far. To …

Multienzyme system in amorphous metal–organic frameworks for intracellular lactate detection

Y Zhang, L Xu, J Ge - Nano Letters, 2022 - ACS Publications
Lactate is an important downstream product of glycolysis in living cells, and its level is highly
related with diseases. On the basis of amorphous metal–organic frameworks (aMOFs), a …

Metal nanoparticles@ covalent organic framework@ enzymes: a universal platform for fabricating a metal–enzyme integrated nanocatalyst

H Zhao, G Liu, Y Liu, X Liu, H Wang… - … Applied Materials & …, 2022 - ACS Publications
Cascade catalysis that combines chemical catalysis and biocatalysis has received extensive
attention in recent years, especially the integration of metal nanoparticles (MNPs) with …