The transition metal-catalysed hydroboration reaction

SJ Geier, CM Vogels, JA Melanson… - Chemical Society …, 2022 - pubs.rsc.org
The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

First-row d-block element-catalyzed carbon–boron bond formation and related processes

SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Inside‐and‐Out Semiconductor Engineering for CO2 Photoreduction: From Recent Advances to New Trends

S Wang, X Han, Y Zhang, N Tian, T Ma… - Small …, 2021 - Wiley Online Library
Photocatalytic CO2 reduction attracts substantial interests for the production of chemical
fuels via solar energy conversion, but the activity, stability, and selectivity of products were …

Hydroamination, Aminoboration, and Carboamination with Electrophilic Amination Reagents: Umpolung-Enabled Regio- and Stereoselective Synthesis of N …

K Hirano, M Miura - Journal of the American Chemical Society, 2022 - ACS Publications
Nitrogen (N) is ubiquitously found in bioactive molecules, pharmaceutical agents, and
organic functional materials. Accordingly, development of new C–N bond-forming catalysis …

Semiconductor Quantum Dots: An Emerging Candidate for CO2 Photoreduction

HL Wu, XB Li, CH Tung, LZ Wu - Advanced Materials, 2019 - Wiley Online Library
As one of the most critical approaches to resolve the energy crisis and environmental
concerns, carbon dioxide (CO2) photoreduction into value‐added chemicals and solar fuels …

Copper-catalyzed borylative difunctionalization of π-systems

A Whyte, A Torelli, B Mirabi, A Zhang, M Lautens - ACS Catalysis, 2020 - ACS Publications
Organoboronates represent a cornerstone functional group in modern synthesis owing to
their unique reactivity and divergent synthetic capability. Copper catalysis has become one …

Chemically and electrochemically catalysed conversion of CO2 to CO with follow-up utilization to value-added chemicals

DU Nielsen, XM Hu, K Daasbjerg, T Skrydstrup - Nature Catalysis, 2018 - nature.com
Carbon dioxide is ubiquitous and a vital molecule for maintaining life on our planet.
However, the ever-increasing emission of anthropogenic CO2 into our atmosphere has …

Diboron (4) compounds: from structural curiosity to synthetic workhorse

EC Neeve, SJ Geier, IAI Mkhalid, SA Westcott… - Chemical …, 2016 - ACS Publications
Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Recent advances in hydrometallation of alkenes and alkynes via the first row transition metal catalysis

J Chen, J Guo, Z Lu - Chinese Journal of Chemistry, 2018 - Wiley Online Library
Hydrometallation of alkenes and alkynes provides a straightforward route to access alkyl‐or
alkenyl‐metal reagents, which have a wide range of applications in organic transformations …

N-heterocyclic carbene complexes of copper, nickel, and cobalt

AA Danopoulos, T Simler, P Braunstein - Chemical reviews, 2019 - ACS Publications
The emergence of N-heterocyclic carbenes as ligands across the Periodic Table had an
impact on various aspects of the coordination, organometallic, and catalytic chemistry of the …