Recent advances in the synthesis and reactivity of MIDA boronates
Organoboron compounds have a wide-range of applications in synthetic methodologies,
natural products, and bioactive molecule synthesis. The sensitivity of boronic acid toward …
natural products, and bioactive molecule synthesis. The sensitivity of boronic acid toward …
Transmetalation of boronic acids and their derivatives: mechanistic elucidation and relevance to catalysis
K Osakada, Y Nishihara - Dalton Transactions, 2022 - pubs.rsc.org
The Suzuki–Miyaura reaction (the cross-coupling reaction of boronic acids with organic
halides catalysed by Pd complexes) has been recognised as a useful synthetic organic …
halides catalysed by Pd complexes) has been recognised as a useful synthetic organic …
Reactivity in nickel‐catalyzed multi‐component sequential reductive cross‐coupling reactions
The nickel‐catalyzed three‐component reductive carbonylation of alkyl halides, aryl halides,
and ethyl chloroformate is described. Ethyl chloroformate is utilized as a safe and readily …
and ethyl chloroformate is described. Ethyl chloroformate is utilized as a safe and readily …
Catalytic Asymmetric Transfer Hydrogenation of Acylboronates: BMIDA as the Privileged Directing Group
X Meng, S Lan, T Chen, H Luo, L Zhu… - Journal of the …, 2024 - ACS Publications
Developing a general, highly efficient, and enantioselective catalytic method for the
synthesis of chiral alcohols is still a formidable challenge. We report in this article the …
synthesis of chiral alcohols is still a formidable challenge. We report in this article the …
Palladium-Catalyzed Oxidative Nonclassical Heck Reaction of Arylhydrazines with Allylic Alcohols via C–N Bond Cleavage: Access to β-Arylated Carbonyl …
X Wang, X Wang, H Pan, X Ming… - The Journal of Organic …, 2022 - ACS Publications
An efficient palladium-catalyzed oxidative nonclassical Heck reaction of arylhydrazines with
allylic alcohols via C–N bond cleavage has been successfully developed. This method …
allylic alcohols via C–N bond cleavage has been successfully developed. This method …
A Boron Scan of Ethyl Acetoacetate Leads to Versatile Building Blocks
A Trofimova, B White, DB Diaz… - Angewandte …, 2024 - Wiley Online Library
Discovered in the 19th century, ethyl acetoacetate has been central to the development of
organic chemistry, including its pedagogy and applications. In this study, we present …
organic chemistry, including its pedagogy and applications. In this study, we present …
Copper‐Catalyzed Borylation of Acyl Chlorides with an Alkoxy Diboron Reagent: A Facile Route to Acylboron Compounds
X Zhang, A Friedrich, TB Marder - Chemistry–A European …, 2022 - Wiley Online Library
Herein, the copper‐catalyzed borylation of readily available acyl chlorides with bis
(pinacolato) diboron,(B2pin2) or bis (neopentane glycolato) diboron (B2neop2) is reported …
(pinacolato) diboron,(B2pin2) or bis (neopentane glycolato) diboron (B2neop2) is reported …
Ruthenium-on-Carbon-Catalyzed Facile Solvent-Free Oxidation of Alcohols: Efficient Progress under Solid–Solid (Liquid)–Gas Conditions
A protocol for the ruthenium-on-carbon (Ru/C)-catalyzed solvent-free oxidation of alcohols,
which proceeds efficiently under solid–solid (liquid)–gas conditions, was developed …
which proceeds efficiently under solid–solid (liquid)–gas conditions, was developed …
Carbonyl Functional Groups in Reaction Development: Carbonylative Cross-Coupling, α-Hydrazination, and CC Cleavage
CH Tien - 2023 - search.proquest.com
The carbonyl motif (C= O) is embedded in various abundant functional groups such as
carboxylic acids, ketones, aldehydes, and many more. The reactivity of the carbonyl group …
carboxylic acids, ketones, aldehydes, and many more. The reactivity of the carbonyl group …