The metal‐catalysed hydrofunctionalisation of alkenes and alkynes provides a convenient
and atom‐economic route to diversely functionalised products with control of regio‐, chemo …

Hydrosilation reactions represent an important class of chemical transformations and there
has been considerable recent interest in expanding the scope of these reactions by …

An efficient Rh (III)-and Ir (III)-catalyzed, chelation-assisted C–H alkynylation of a broad
scope of (hetero) arenes has been developed using hypervalent iodine-alkyne reagents …

Terminal alkenes are readily available functional groups which appear in α‐olefins
produced by the chemical industry, and they appear in the products of many contemporary …

Many efficient stereo-and regio-selective methodologies for synthesis of substituted
vinylsilanes have been reported, involving mostly classical stoichiometric routes as well as …

Direct C–H amination of arenes offers a straightforward route to aniline compounds without
necessitating aryl (pseudo) halides as the starting materials. The recent development in this …

The mechanism of hydrosilylation using the highly active precatalyst Karstedt's precatalyst
(Pt x (MvinylMvinyl) y, MvinylMvinyl= divinyltetramethyldisiloxane) was investigated using …

Publisher Summary This chapter discusses about compounds or complexes that facilitate
hydrosilation. The word ''true catalyst''is used where the actual catalytic species is positively …

This review summarizes the advances produced in the last 5 years in the use of mixed
ligands containing at least one phosphino and one pyridyl or related group (bipyridyl …

Catalytic CO2 hydrosilylation is a thermodynamically favored chemical process that could be
potentially applied to large-scale transformations of this greenhouse gas. During the last …