Molecular actinide compounds with soft chalcogen ligands
M Ephritikhine - Coordination Chemistry Reviews, 2016 - Elsevier
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A terminal neptunium (V)–mono (oxo) complex
MS Dutkiewicz, CAP Goodwin, M Perfetti, AJ Gaunt… - Nature Chemistry, 2022 - nature.com
Neptunium was the first actinide element to be artificially synthesized, yet, compared with its
more famous neighbours uranium and plutonium, is less conspicuously studied. Most …
more famous neighbours uranium and plutonium, is less conspicuously studied. Most …
The strength of actinide–element bonds from the quantum theory of atoms-in-molecules
QR Huang, JR Kingham, N Kaltsoyannis - Dalton Transactions, 2015 - pubs.rsc.org
[AnX3] 2 (μ–η2: η2-N2)(An= Th–Pu; X= F, Cl, Br, Me, H, OPh) have been studied using
relativistic density functional theory. Geometric and vibrational data suggest that metal→ N2 …
relativistic density functional theory. Geometric and vibrational data suggest that metal→ N2 …
f-Block reactions of metal cations with carbon dioxide studied by inductively coupled plasma tandem mass spectrometry
f-Block chemistry offers an opportunity to test current knowledge of chemical reactivity. The
energy dependence of lanthanide cation (Ln+= Ce+, Pr+, Nd+–Eu+) and actinide cation …
energy dependence of lanthanide cation (Ln+= Ce+, Pr+, Nd+–Eu+) and actinide cation …
[HTML][HTML] Bond energies of ThO+ and ThC+: A guided ion beam and quantum chemical investigation of the reactions of thorium cation with O2 and CO
RM Cox, M Citir, PB Armentrout, SR Battey… - The Journal of …, 2016 - pubs.aip.org
Kinetic energy dependent reactions of Th+ with O 2 and CO are studied using a guided ion
beam tandem mass spectrometer. The formation of ThO+ in the reaction of Th+ with O 2 is …
beam tandem mass spectrometer. The formation of ThO+ in the reaction of Th+ with O 2 is …
Spectroscopy and structure of the simplest actinide bonds
MC Heaven, BJ Barker, IO Antonov - The Journal of Physical …, 2014 - ACS Publications
Understanding the influence of electrons in partially filled f-and d-orbitals on bonding and
reactivity is a key issue for actinide chemistry. This question can be investigated by using a …
reactivity is a key issue for actinide chemistry. This question can be investigated by using a …
Uranium redox and deposition transitions embedded in deep‐time geochemical models and mineral chemistry networks
Uranium (U) is an important global energy resource and a redox sensitive trace element that
reflects changing environmental conditions and geochemical cycling. The redox evolution of …
reflects changing environmental conditions and geochemical cycling. The redox evolution of …
[HTML][HTML] Bond energy of ThN+: A guided ion beam and quantum chemical investigation of the reactions of thorium cation with N2 and NO
RM Cox, A Kafle, PB Armentrout… - The Journal of chemical …, 2019 - pubs.aip.org
Kinetic-energy dependent reactions of Th+ with N 2 and NO are studied using a guided ion
beam tandem mass spectrometer. The formation of ThO+ in the reaction of Th+ with NO is …
beam tandem mass spectrometer. The formation of ThO+ in the reaction of Th+ with NO is …
Activation of CO2 by Actinide Cations (Th+, U+, Pu+, and Am+) as Studied by Guided Ion Beam and Triple Quadrupole Mass Spectrometry
RM Cox, K Harouaka, M Citir… - Inorganic Chemistry, 2022 - ACS Publications
Reactions of CO2 with Th+ have been studied using guided ion beam tandem mass
spectrometry (GIBMS) and with An+ (An+= Th+, U+, Pu+, and Am+) using triple quadrupole …
spectrometry (GIBMS) and with An+ (An+= Th+, U+, Pu+, and Am+) using triple quadrupole …
Predissociation-based measurements of bond dissociation energies: US2, OUS, and USe
KH Tomchak, JJ Sorensen, E Tieu… - The Journal of Chemical …, 2024 - pubs.aip.org
The uranium-containing molecules US 2, OUS, and USe have been investigated using a
pulsed laser ablation supersonic beam molecular source with time-of-flight mass …
pulsed laser ablation supersonic beam molecular source with time-of-flight mass …