Molecular actinide compounds with soft chalcogen ligands

M Ephritikhine - Coordination Chemistry Reviews, 2016 - Elsevier
Molecular actinide compounds with soft chalcogen ligands - ScienceDirect Skip to main
contentSkip to article Elsevier logo Journals & Books Search RegisterSign in View PDF …

A terminal neptunium (V)–mono (oxo) complex

MS Dutkiewicz, CAP Goodwin, M Perfetti, AJ Gaunt… - Nature Chemistry, 2022 - nature.com
Neptunium was the first actinide element to be artificially synthesized, yet, compared with its
more famous neighbours uranium and plutonium, is less conspicuously studied. Most …

The strength of actinide–element bonds from the quantum theory of atoms-in-molecules

QR Huang, JR Kingham, N Kaltsoyannis - Dalton Transactions, 2015 - pubs.rsc.org
[AnX3] 2 (μ–η2: η2-N2)(An= Th–Pu; X= F, Cl, Br, Me, H, OPh) have been studied using
relativistic density functional theory. Geometric and vibrational data suggest that metal→ N2 …

f-Block reactions of metal cations with carbon dioxide studied by inductively coupled plasma tandem mass spectrometry

RM Cox, KM Melby, AD French… - Physical Chemistry …, 2024 - pubs.rsc.org
f-Block chemistry offers an opportunity to test current knowledge of chemical reactivity. The
energy dependence of lanthanide cation (Ln+= Ce+, Pr+, Nd+–Eu+) and actinide cation …

[HTML][HTML] Bond energies of ThO+ and ThC+: A guided ion beam and quantum chemical investigation of the reactions of thorium cation with O2 and CO

RM Cox, M Citir, PB Armentrout, SR Battey… - The Journal of …, 2016 - pubs.aip.org
Kinetic energy dependent reactions of Th+ with O 2 and CO are studied using a guided ion
beam tandem mass spectrometer. The formation of ThO+ in the reaction of Th+ with O 2 is …

Spectroscopy and structure of the simplest actinide bonds

MC Heaven, BJ Barker, IO Antonov - The Journal of Physical …, 2014 - ACS Publications
Understanding the influence of electrons in partially filled f-and d-orbitals on bonding and
reactivity is a key issue for actinide chemistry. This question can be investigated by using a …

Uranium redox and deposition transitions embedded in deep‐time geochemical models and mineral chemistry networks

EK Moore, J Li, A Zhang, J Hao… - Geochemistry …, 2024 - Wiley Online Library
Uranium (U) is an important global energy resource and a redox sensitive trace element that
reflects changing environmental conditions and geochemical cycling. The redox evolution of …

[HTML][HTML] Bond energy of ThN+: A guided ion beam and quantum chemical investigation of the reactions of thorium cation with N2 and NO

RM Cox, A Kafle, PB Armentrout… - The Journal of chemical …, 2019 - pubs.aip.org
Kinetic-energy dependent reactions of Th+ with N 2 and NO are studied using a guided ion
beam tandem mass spectrometer. The formation of ThO+ in the reaction of Th+ with NO is …

Activation of CO2 by Actinide Cations (Th+, U+, Pu+, and Am+) as Studied by Guided Ion Beam and Triple Quadrupole Mass Spectrometry

RM Cox, K Harouaka, M Citir… - Inorganic Chemistry, 2022 - ACS Publications
Reactions of CO2 with Th+ have been studied using guided ion beam tandem mass
spectrometry (GIBMS) and with An+ (An+= Th+, U+, Pu+, and Am+) using triple quadrupole …

Predissociation-based measurements of bond dissociation energies: US2, OUS, and USe

KH Tomchak, JJ Sorensen, E Tieu… - The Journal of Chemical …, 2024 - pubs.aip.org
The uranium-containing molecules US 2, OUS, and USe have been investigated using a
pulsed laser ablation supersonic beam molecular source with time-of-flight mass …