Phase transitions in polymer blends and block copolymer melts: Some recent developments

K Binder - Theories and mechanism of phase transitions …, 2005 - Springer
The classical concepts about unmixing of polymer blends (Flory-Huggins theory) and about
mesophase ordering in block copolymers (Leibler's theory) are briefly reviewed and their …

Diffusion in polymeric systems–A review on free volume theory

J Sharma, K Tewari, RK Arya - Progress in Organic Coatings, 2017 - Elsevier
This review paper deals the history and development of various theories to predict the
diffusion in polymeric systems. The basis and application of various theories with the …

Polymer free volume and its connection to the glass transition

RP White, JEG Lipson - Macromolecules, 2016 - ACS Publications
In this Perspective we summarize the most widely used definitions of free volume and
illustrate the differences between them, including the important distinction between total free …

Polymer-polymer phase behavior

FS Bates - Science, 1991 - science.org
Different polymers can be combined into a single material in many ways, which can lead to a
wide range of phase behaviors that directly influence the associated physical properties and …

Application of molecular simulation to derive phase diagrams of binary mixtures

CF Fan, BD Olafson, M Blanco, SL Hsu - Macromolecules, 1992 - ACS Publications
The miscibility behavior of three binary mixtures, solvent with solvent, polymer with solvent,
and polymer with polymer, was studied by use of a combination of the Flory-Huggins theory …

Effect of monomer structure and compressibility on the properties of multicomponent polymer blends and solutions: 1. Lattice cluster theory of compressible systems

J Dudowicz, KF Freed - Macromolecules, 1991 - ACS Publications
The lattice cluster theory is extended to describe multicomponent mixturesof polymers with
monomers that have internal structuresand therefore extend over several lattice sites. One or …

50th Anniversary Perspective: Phase Behavior of Polymer Solutions and Blends

P Knychała, K Timachova, M Banaszak… - …, 2017 - ACS Publications
We summarize our knowledge of the phase behavior of polymer solutions and blends using
a unified approach. We begin with a derivation of the Flory–Huggins expression for the …

[图书][B] The science of polymer molecules

RH Boyd, PJ Phillips - 1993 - books.google.com
This book is an introduction to polymers that focuses on the synthesis, structure, and
properties of the individual molecules that constitute polymeric materials. The authors …

Toward the Development of “CO2-philic” Hydrocarbons. 1. Use of Side-Chain Functionalization to Lower the Miscibility Pressure of Polydimethylsiloxanes in CO2

R Fink, D Hancu, R Valentine… - The Journal of Physical …, 1999 - ACS Publications
Previous fundamental work on the solvent properties of carbon dioxide by the research
groups of McHugh, DeSimone, Johnston, and Eckert has been used as a road map for the …

Effect of monomer structure and compressibility on the properties of multicomponent polymer blends and solutions. 2. Application to binary blends

J Dudowicz, MS Freed, KF Freed - Macromolecules, 1991 - ACS Publications
The general lattice cluster theory of corrections to classic Flory-Huggins theory from paper 1
is applied to compressible binary polymer blends. The properties considered are the small …