Photoelectron spectroscopy has long been a powerful method in the toolbox of experimental
physical chemistry and molecular physics. Recent improvements in coincidence methods …

For decades one has strived to synthesize a compound with the longest covalent C− C bond
applying predominantly steric hindrance and/or strain to achieve this goal. On the other …

Helium droplets are unique hosts for isolating diverse molecular ions for infrared
spectroscopic experiments. Recently, it was found that electron impact ionization of ethylene …

Recent experimental and computational advances have heralded huge progress in the
range and the detail of the database pertaining to photoinduced C–H bond fission …

We have investigated the photoionization of ammonia borane (AB) and determined
adiabatic ionization energy to be 9.26±0.03 eV for the X+ 2E← X 1A1 transition. Although …

Chemical processing in the stratospheres of the gas giants is driven by incident vacuum
ultraviolet (VUV) light. Ethane is an important constituent in the atmospheres of the gas …

Ring strain energy is a very well documented feature of neutral cycloalkanes, and influences
their structural, thermochemical and reactivity properties. In this work, we apply density …

We present a procedure, based on established principles, to accurately determine the
ionisation energies of medium-sized to large polyatomic molecules in supersonic beams …

The calculation of hyperfine coupling constants is a challenging task in balancing accuracy
and computational effort. While previous work has shown the importance of electron …

Spectroscopy of transient anions and radicals by gated and accelerated time-of-flight
experiment is a new spectrometer developed in UCLouvain. This instrument measures high …