Photoactive ruthenium nitrosyls: Effects of light and potential application as NO donors

MJ Rose, PK Mascharak - Coordination chemistry reviews, 2008 - Elsevier
In recent years, various exogenous nitric oxide (NO) donors have been synthesized to
modulate NO concentrations in cellular environments and control physiological processes …

Biological activity of ruthenium nitrosyl complexes

E Tfouni, DR Truzzi, A Tavares, AJ Gomes… - Nitric oxide, 2012 - Elsevier
Nitric oxide plays an important role in various biological processes, such as
neurotransmission, blood pressure control, immunological responses, and antioxidant …

Sensitization of ruthenium nitrosyls to visible light via direct coordination of the dye resorufin: trackable NO donors for light-triggered NO delivery to cellular targets

MJ Rose, NL Fry, R Marlow, L Hinck… - Journal of the …, 2008 - ACS Publications
Three nitrosyl-dye conjugates, namely,[(Me2bpb) Ru (NO)(Resf)](1-Resf),[(Me2bQb) Ru
(NO)(Resf)](2-Resf), and [((OMe) 2bQb) Ru (NO)(Resf)](3-Resf) have been synthesized via …

Synthesis, Structure, and Reactivity of Acid‐Free Neutral Oxoborane

H Wang, J Zhang, J Yang, Z Xie - Angewandte Chemie, 2021 - Wiley Online Library
An efficient synthesis of an acid‐free neutral oxoborane of the type carboranyl‐B (carbene)=
O has been developed via a serendipitous discovery from the reaction of 1, 2‐[BBr …

Mutual effects in the chemical properties of the ruthenium metal center and ancillary ligands upon coordination

JC Toledo, BSL Neto, DW Franco - Coordination chemistry reviews, 2005 - Elsevier
The mutual changes induced in both metal center and selected ligands kinetics and
thermodynamic properties, as a consequence of the coordination, are discussed in terms of …

Synthesis, spectroscopic analysis and photolabilization of water-soluble ruthenium (III)–nitrosyl complexes

AC Merkle, AB McQuarters, N Lehnert - Dalton Transactions, 2012 - pubs.rsc.org
In this paper, the synthesis, structural and spectroscopic characterization of a series of new
Ru (III)–nitrosyls of {RuNO} 6 type with the coligand TPA (tris (2-pyridylmethyl) amine) are …

Electronic structure alternatives in nitrosylruthenium complexes

GK Lahiri, W Kaim - Dalton Transactions, 2010 - pubs.rsc.org
Coordination compounds [Ru (NO) Ln] containing an electro-active metal and potentially
non-innocent ligands NO (and L) can have ground state electronic structures formulated as …

Photosolvolysis of cis-[Ru(α-diimine)2(4-aminopyridine)2]2+ Complexes: Photophysical, Spectroscopic, and Density Functional Theory Analysis

MR Camilo, CR Cardoso, RM Carlos… - Inorganic …, 2014 - ACS Publications
The photochemical and photophysical properties of the cis-[RuII (α-diimine) 2 (4-APy) 2] 2+
complexes, where α-diimine= 1, 10-phenanthroline (phen) and 4-APy= 4-aminopyridine I, 4 …

Nitric oxide production by visible light irradiation of aqueous solution of nitrosyl ruthenium complexes

MG Sauaia, RG de Lima, AC Tedesco… - Inorganic …, 2005 - ACS Publications
[RuIIL (NH3) 4 (pz) RuII (bpy) 2 (NO)](PF6) 5 (L is NH3, py, or 4-acpy) was prepared with
good yields in a straightforward way by mixing an equimolar ratio of cis-[Ru (NO2)(bpy) 2 …

Ruthenium nitrosyls derived from tetradentate ligands containing carboxamido-N and phenolato-O donors: syntheses, structures, photolability, and time dependent …

NL Fry, MJ Rose, DL Rogow, C Nyitray, M Kaur… - Inorganic …, 2010 - ACS Publications
In order to examine the role (s) of designed ligands on the NO photolability of {Ru-NO} 6
nitrosyls, a set of three nitrosyls with ligands containing two carboxamide groups along with …