Over the past two decades, the vibrational Stark effect has become an important tool to
measure and analyze the in situ electric field strength in various chemical environments with …

Conspectus The structure and reactivity of a molecule in the condensed phase are governed
by its intermolecular interactions with the surrounding environment. The multipole expansion …

The relation between the vibrational properties and the electrostatic situations of the
vibrating functional group is useful to predict vibrational spectroscopic features based on, for …

We consider a water molecule under tight confinement in the small‐sized fullerenes (C 28
_28, C 30 _30, C 32 _32) within the density functional theory (DFT) calculations with suitable …

Ammonia is special. It is nonplanar, yet in v= 1 of the umbrella mode (ν2) its inversion motion
is faster than J= 0↔ 1 rotation. Does the simplicity of the Chemist's concept of an electric …

The study of amorphous solid water (ASW) films on solid substrates has been instrumental
in understanding the structure and morphology of water ices. In addition, they have the …

The acyclic form of monosaccharides exists in a structural equilibrium, with aldose having
the aldehyde group and ketose the ketone group (ketose–aldose equilibrium). A basic …

This article focuses on the manipulation of molecular bond lengths by an external electric
field. A uniform dc electric field with strength up to 1.5× 108 V/m was applied to HCl–H2O …

Tuning the anionic solvation structure and dynamic processes at solid‒liquid interfaces are
critical yet challenging for stabilizing Zn metal anodes in Zn ion batteries. Here, we …

This book describes the manipulation of molecular properties, such as orientation, structure,
and dynamics, of small molecules and molecular clusters isolated in cold inert matrices by …