Organic synthesis using nitroxides

D Leifert, A Studer - Chemical Reviews, 2023 - ACS Publications
Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

Nitroxide-mediated polymerization

J Nicolas, Y Guillaneuf, C Lefay, D Bertin… - Progress in Polymer …, 2013 - Elsevier
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …

Nitroxides: applications in synthesis and in polymer chemistry

L Tebben, A Studer - Angewandte Chemie International Edition, 2011 - Wiley Online Library
This Review describes the application of nitroxides to synthesis and polymer chemistry. The
synthesis and physical properties of nitroxides are discussed first. The largest section …

Nitroxide-mediated radical polymerization: limitations and versatility

RB Grubbs - Polymer Reviews, 2011 - Taylor & Francis
Since its introduction in the early 1990s, nitroxide-mediated radical polymerization (NMP)
has been widely adopted for the preparation of a panoply of new polymer architectures …

Plasmon-Assisted Chemistry Using Chiral Gold Helicoids: Toward Asymmetric Organic Catalysis

P Bainova, JP Joly, M Urbanova, D Votkina… - ACS …, 2023 - ACS Publications
Gold nanoparticles with shape-determined chirality enable the attainment of plasmon-
associated optical activities exceeding those exhibited by all previously known natural …

A critical assessment of the kinetics and mechanism of initiation of radical polymerization with commercially available dialkyldiazene initiators

G Moad - Progress in Polymer Science, 2019 - Elsevier
The dialkyldiazene or azo-compound initiators, which include azonitriles such as azobis
(isobutyronitrile)(AIBN), are one of the most important classes of initiator being widely used …

Multicomponent Synthesis of S-Benzyl Dithiocarbamates from para-Quinone Methides and Their Biological Evaluation for the Treatment of Alzheimer's Disease

R Venkatesh, G Shankar, AC Narayanan… - The Journal of …, 2022 - ACS Publications
Multicomponent synthesis of biologically relevant S-benzyl dithiocarbamates from para-
quinone methides, amines, and carbon disulfide are described under catalyst and additive …

Nitroxide: Anwendungen in der Synthese und in der Polymerchemie

L Tebben, A Studer - Angewandte Chemie, 2011 - Wiley Online Library
Nitroxide werden in der Synthese und in der Polymerchemie verwendet. In diesem Aufsatz
werden zunächst Methoden zur Herstellung von Nitroxiden und deren physikalische …

Synthesis of N,S-Heterocycles and Dithiocarbamates by the Reaction of Dithiocarbamic Acids and S-Alkyl Dithiocarbamates with Nitroepoxides

A Ziyaei Halimehjani, Y Lotfi Nosood - Organic letters, 2017 - ACS Publications
A facile and efficient procedure for the synthesis of substituted thiazole-2 (3 H)-thiones and
thiazolidine-2-thiones by the reaction of primary amines, carbon disulfide, and nitroepoxides …

Synthesis of dithiocarbamate by Markovnikov addition reaction in aqueous medium

AZ Halimehjani, K Marjani, A Ashouri - Green Chemistry, 2010 - pubs.rsc.org
Synthesis of dithiocarbamate by Markovnikov addition reaction in aqueous medium - Green
Chemistry (RSC Publishing) DOI:10.1039/C004711B Royal Society of Chemistry View PDF …