[HTML][HTML] On the role of spin correlation in the formation, decay, and detection of long-lived, intramolecular charge-transfer states

JW Verhoeven - Journal of Photochemistry and Photobiology C …, 2006 - Elsevier
This review presents some of the efforts that have been made over the last decades to
produce systems in which photo-excitation leads to one or more intramolecular electron …

Long‐Lived Charge‐Transfer States in Compact Donor–Acceptor Dyads

JW Verhoeven, HJ van Ramesdonk… - …, 2005 - Wiley Online Library
Photoinduced electron transfer is a widely applied method to convert photon energy into a
useful (electro) chemical potential, both in nature and in artificial devices. There is a …

Charge shift and triplet state formation in the 9-mesityl-10-methylacridinium cation

AC Benniston, A Harriman, P Li… - Journal of the …, 2005 - ACS Publications
The target donor− acceptor compound forms an acridinium-like, locally excited (LE) singlet
state on illumination with blue or near-UV light. This LE state undergoes rapid charge …

Spin–orbit charge recombination intersystem crossing in phenothiazine–anthracene compact dyads: effect of molecular conformation on electronic coupling …

Y Hou, T Biskup, S Rein, Z Wang… - The Journal of …, 2018 - ACS Publications
Phenothiazine (PTZ)–anthracene (An) compact electron donor/acceptor dyads were
synthesized. The molecular conformation was constrained by rotation restriction to achieve …

Solvent-controlled intramolecular electron transfer in ionic liquids

X Li, M Liang, A Chakraborty, M Kondo… - The Journal of …, 2011 - ACS Publications
The rates of excited-state intramolecular electron transfer in 9-(4-biphenyl)-10-
methylacridinium (BPAc+), crystal violet lactone (CVL), and bianthryl have been measured …

Carboxy SNARF-4F as a fluorescent pH probe for ensemble and fluorescence correlation spectroscopies

N Marcotte, AM Brouwer - The Journal of Physical Chemistry B, 2005 - ACS Publications
The optical spectroscopic properties of 1, 4 (and 5)-benzenedicarboxylic acid, 2-[10-
(dimethylamino)-4-fluoro-3-oxo-3H-benzo [c] xanthen-7-yl](carboxy SNARF-4F), a …

Tuneable white fluorescence from intramolecular exciplexes

J Karpiuk, E Karolak, J Nowacki - Physical Chemistry Chemical …, 2010 - pubs.rsc.org
Crystal violet lactone (CVL) in solution displays unusually broad (FWHM> 9100 cm− 1) dual
fluorescence with the characteristics of white light. The emission combines a blue CT band …

Dual fluorescence from two polar excited states in one molecule. Structurally additive photophysics of crystal violet lactone

J Karpiuk - The Journal of Physical Chemistry A, 2004 - ACS Publications
Crystal violet lactone (CVL) emits in aprotic solvents at room temperature single (A band,
low polar solvents) or dual (A and B bands, medium and highly polar solvents) fluorescence …

Electrochemical Generation of Excited Intramolecular Charge‐Transfer States

A Kapturkiewicz - ChemElectroChem, 2017 - Wiley Online Library
Excited intramolecular charge‐transfer states have been attracting significant attention in
recent decades, as they are crucial for different optoelectronic applications including the …

Stability of Rhodamine Lactone Cycle in Solutions: Chain–Ring Tautomerism, Acid–Base Equilibria, Interaction with Lewis Acids, and Fluorescence

OM Obukhova, NO Mchedlov-Petrossyan… - Colorants, 2022 - mdpi.com
The equilibrium between different tautomers that can be colored or colorless is an important
feature for rhodamine dyes. Presently, this phenomenon is mostly discussed for rhodamine …