Molecular views on mechanisms of Brønsted acid-catalyzed reactions in zeolites

C Chizallet, C Bouchy, K Larmier… - Chemical …, 2023 - ACS Publications
The Brønsted acidity of proton-exchanged zeolites has historically led to the most impactful
applications of these materials in heterogeneous catalysis, mainly in the fields of …

Continuous Flow Upgrading of Selected C2–C6 Platform Chemicals Derived from Biomass

R Gerardy, DP Debecker, J Estager, P Luis… - Chemical …, 2020 - ACS Publications
The ever increasing industrial production of commodity and specialty chemicals inexorably
depletes the finite primary fossil resources available on Earth. The forecast of population …

Highly Selective Transformation of Biomass Derivatives to Valuable Chemicals by Single‐Atom Photocatalyst Ni/TiO2

L Xiong, H Qi, S Zhang, L Zhang, X Liu… - Advanced …, 2023 - Wiley Online Library
Abstract Selective C C cleavage of the biomass derivative glycerol under mild conditions is
recognized as a promising yet challenging synthesis route to produce value‐added …

Engineering UiO‐66 metal organic framework for heterogeneous catalysis

A Dhakshinamoorthy, A Santiago‐Portillo… - …, 2019 - Wiley Online Library
Metal organic frameworks (MOFs) are currently attracting considerable attention as
heterogeneous catalysts at moderate temperatures, mainly for liquid‐phase reactions. Since …

Probing zeolites by vibrational spectroscopies

S Bordiga, C Lamberti, F Bonino, A Travert… - Chemical Society …, 2015 - pubs.rsc.org
This review addresses the most relevant aspects of vibrational spectroscopies (IR, Raman
and INS) applied to zeolites and zeotype materials. Surface Brønsted and Lewis acidity and …

Carbocation chemistry confined in zeolites: spectroscopic and theoretical characterizations

W Chen, X Yi, Z Liu, X Tang, A Zheng - Chemical Society Reviews, 2022 - pubs.rsc.org
Acid-catalyzed reactions inside zeolites are one type of broadly applied industrial reactions,
where carbocations are the most common intermediates of these reaction processes …

Hydrophobic solid acids and their catalytic applications in green and sustainable chemistry

F Liu, K Huang, A Zheng, FS Xiao, S Dai - ACS Catalysis, 2018 - ACS Publications
Acid catalysts are widely used in petrochemical reactions, the synthesis of fine chemicals,
and biomass conversions in industry. To comply with the principles of green and sustainable …

Heterogeneous Diels–Alder catalysis for biomass-derived aromatic compounds

AE Settle, L Berstis, NA Rorrer, Y Roman-Leshkóv… - Green …, 2017 - pubs.rsc.org
In this tutorial review, we provide an overview of heterogeneous Diels–Alder catalysis for the
production of lignocellulosic biomass-derived aromatic compounds. Diels–Alder reactions …

Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials

H Li, Z Fang, RL Smith Jr, S Yang - Progress in Energy and Combustion …, 2016 - Elsevier
Mono-functional catalytic materials are used for many types of chemical transformations, but
are tedious for delivering products from multiple-step reactions required for the valorization …

Tuning the aluminum distribution in zeolites to increase their performance in acid‐catalyzed reactions

J Dědeček, E Tabor, S Sklenak - ChemSusChem, 2019 - Wiley Online Library
The organization of Al atoms in the framework of Si‐rich zeolites is very important and
includes two classes:(i) the Al siting that determines which individual, crystallographically …