Bond activations assisted by redox active ligand scaffolds
FF Khan, AD Chowdhury… - European Journal of …, 2020 - Wiley Online Library
Redox active ligands are an integral part of many biological events and significant natural
processes. Transformations assisted by such ligands gather the limelight owing to their …
processes. Transformations assisted by such ligands gather the limelight owing to their …
Redox induced oxidative C–C coupling of non-innocent bis (heterocyclo) methanides
Redox driven C–C bond formation has gained recent attention over the traditional sequence
of oxidative addition, insertion and reductive elimination reactions. In this regard, the …
of oxidative addition, insertion and reductive elimination reactions. In this regard, the …
Diverse Functionalization of Ruthenium-Chelated 2-Picolylamines: Oxygenation, Dehydrogenation, Cyclization, and N-Dealkylation
S Panda, A Singha Hazari, M Gogia… - Inorganic Chemistry, 2020 - ACS Publications
“Chemical noninnocence” of metal-coordinated 2-picolylamine (PA) derivatives has been
introduced upon its reaction with the metal precursor [RuII (Cl)(H)(CO)(PPh3) 3] under basic …
introduced upon its reaction with the metal precursor [RuII (Cl)(H)(CO)(PPh3) 3] under basic …
Indazole-Derived Mono-/Diruthenium and Heterotrinuclear Complexes: Switchable Binding Mode, Electronic Form, and Anion Sensing Events
The article deals with the newer classes of mononuclear:[(acac) 2RuIII (H-Iz)(Iz–)] 1,[(acac)
2RuIII (H-Iz) 2] ClO4 [1] ClO4/[1′] ClO4, and [(bpy) 2RuII (H-Iz)(Iz–)] ClO4 [2] ClO4, mixed …
2RuIII (H-Iz) 2] ClO4 [1] ClO4/[1′] ClO4, and [(bpy) 2RuII (H-Iz)(Iz–)] ClO4 [2] ClO4, mixed …
Diverse Coordination Modes and Bidirectional Noninnocence of Pyridyl-β-diketonate on Ruthenium Platforms as a Function of Coligands
The article demonstrated diverse binding modes of deprotonated 1, 3-di (2-pyridinyl)-1, 3-
propanedione (HL)(κ2-[O, O]−, κ2-[N, O]−, and μ-bis-κ2-[N, O]−) on selective ruthenium …
propanedione (HL)(κ2-[O, O]−, κ2-[N, O]−, and μ-bis-κ2-[N, O]−) on selective ruthenium …
Noninnocence of the deprotonated 1, 2-bis ((1 H-pyrrol-2-yl) methylene) hydrazine bridge in diruthenium frameworks–a function of co-ligands
The article deals with the sensitive electronic forms in accessible redox states of structurally
and spectroscopically authenticated deprotonated 1, 2-bis ((1H-pyrrol-2-yl) methylene) …
and spectroscopically authenticated deprotonated 1, 2-bis ((1H-pyrrol-2-yl) methylene) …
A facile approach to C-functionalized β-ketoimine compounds via terminal alkylation of a tetralithiated intermediate
S Zhou, X Xu, X Zhu, Y Zheng, S Chen… - Organic & Biomolecular …, 2022 - pubs.rsc.org
A series of C-functionalized β-ketoimine compounds at the terminal methyl groups of the β-
ketoimine precursor LphH2 (Lph= C6H4 [NC (Me) CHC (Me) O] 2) were prepared. This …
ketoimine precursor LphH2 (Lph= C6H4 [NC (Me) CHC (Me) O] 2) were prepared. This …
Electronic impact of ancillary ligand on the oxygenation profile of ruthenium coordinated β-diketiminate
The recent developments in the direction of metal chelation assisted diverse mode of
functionalization of β-diketiminate (nacnac) led to the present deliberation of C (sp 2)–H …
functionalization of β-diketiminate (nacnac) led to the present deliberation of C (sp 2)–H …
Redox Non‐Innocence and Isomer‐Specific Oxidative Functionalization of Ruthenium‐Coordinated β‐Ketoiminate
This article deals with isomeric ruthenium complexes [RuIII (LR) 2 (acac)](S= 1/2) involving
unsymmetric β‐ketoiminates (AcNac)(LR= R‐AcNac, R= H (1), Cl (2), OMe (3); acac …
unsymmetric β‐ketoiminates (AcNac)(LR= R‐AcNac, R= H (1), Cl (2), OMe (3); acac …
Redox activity as a tool for bond activations and functionalizations
Abstract “Redox active ligand” assisted/controlled bond transformation is the contemporary
approach as an alternative to the classical metal-based transformations. The introduction of …
approach as an alternative to the classical metal-based transformations. The introduction of …