Making expensive dirhodium (II) catalysts cheaper: Rh (II) recycling methods

NR Candeias, CAM Afonso, PMP Gois - Organic & biomolecular …, 2012 - pubs.rsc.org
Dirhodium (II) catalysts have been widely used as a remarkable tool in organic synthesis,
ultimately resulting in a myriad of transformations and formation of a wide variety of …

Metals in medicine: therapeutic agents

A Mukherjee, PJ Sadler - Wiley Encyclopedia of Chemical …, 2007 - Wiley Online Library
Within the emerging field of medicinal inorganic chemistry, the realization that metal
complexes can be designed as both therapeutic and diagnostic agents with novel …

Free Rhodium (II) citrate and rhodium (II) citrate magnetic carriers as potential strategies for breast cancer therapy

MLB Carneiro, ES Nunes, RCA Peixoto… - Journal of …, 2011 - Springer
Abstract Background Rhodium (II) citrate (Rh 2 (H 2 cit) 4) has significant antitumor,
cytotoxic, and cytostatic activity on Ehrlich ascite tumor. Although toxic to normal cells, its …

Tribenzyltin carboxylates as anticancer drug candidates: effect on the cytotoxicity, motility and invasiveness of breast cancer cell lines

T Anasamy, CK Thy, KM Lo, CF Chee, SK Yeap… - European Journal of …, 2017 - Elsevier
This study seeks to investigate the relationship between the structural modification and
bioactivity of a series of tribenzyltin complexes with different ligands and substitutions …

Self‐Supported Heterogeneous Dirhodium (II) Catalyst for Nitrene and Carbene Transfer Reactions

V Satheesh, I Alahakoon, KK Shrestha… - European Journal of …, 2024 - Wiley Online Library
The bimetallic rhodium (II) paddlewheel (Rh2A4) complex is one of the most reactive
classes of rhodium catalysts, well‐renowned for the most demanding carbene‐and nitrene …

Synthesis, spectral and structural characterization of dinuclear rhodium (II) complexes of the anticonvulsant drug valproate with theophylline and caffeine

AL Abuhijleh, HA Ali, AH Emwas - Journal of Organometallic Chemistry, 2009 - Elsevier
The dinuclear complex tetra (μ-valproato) dirhodium (II), Rh2 (valp) 4 (1), and its bis-adducts
with theophylline, Rh2 (valp) 4 (ThH) 2 (4), or caffeine, Rh2 (valp) 4 (Caf) 2 (5), have been …

Redox-regulated Inhibition of T7 RNA polymerase via establishment of disulfide linkages by substituted Dppz dirhodium (II, II) complexes

JD Aguirre, HT Chifotides, AM Angeles-Boza… - Inorganic …, 2009 - ACS Publications
The series of dirhodium (II) complexes cis-[Rh2 (O2CCH3) 2 (R1R2dppz) 2] 2+ 1− 6 (R1=
R2= H, MeO, Me, Cl, NO2 for 1− 4, 6, respectively, and R1= H, R2= CN for 5), coordinated to …

Unprecedented Head-to-Head Right-Handed Cross-Links between the Antitumor Bis(μ-N,N'-di-p-tolylformamidinate) Dirhodium(II,II) Core and the Dinucleotide d …

HT Chifotides, KR Dunbar - Journal of the American Chemical …, 2007 - ACS Publications
Reactions of the anticancer active compound cis-[Rh2 (DTolF) 2 (CH3CN) 6](BF4) 2 with 9-
ethyladenine (9-EtAdeH) or the dinucleotide d (ApA) proceed with bridging adenine bases …

Development of a promising antitumor compound based on rhodium (II) succinate associated with iron oxide nanoparticles coated with lauric acid/albumin hybrid …

MO Silva, MLB Carneiro, JLN Siqueira… - … of nanoscience and …, 2018 - ingentaconnect.com
In this study, we report the synthesis and characterization of a new rhodium (II) succinate
complex (Rh2 (suc) 4) and its immobilization on lauric acid bilayer-coated maghemite …

Conformational studies on chiral rhodium complexes by ECD and VCD spectroscopy

G Szilvágyi, Z Majer, E Vass, M Hollósi - Chirality, 2011 - Wiley Online Library
This article reports vibrational circular dichroism (VCD) and electronic circular dichroism
(ECD) spectroscopic studies in acetonitrile on the chiral Rh2 (O‐Phe‐Cbz) 1 (OAc) 3 and …