Chemistry with methane: concepts rather than recipes

H Schwarz - Angewandte Chemie International Edition, 2011 - Wiley Online Library
Four seemingly simple transformations related to the chemistry of methane will be
addressed from mechanistic and conceptual points of view: 1) metal‐mediated …

Selective activation of alkanes by gas-phase metal ions

J Roithova, D Schroder - Chemical reviews, 2010 - ACS Publications
The importance of the selective activation of alkanes for science and technology in the
forthcoming decades does not need to be explicitly pointed out in this thematic issue of …

How and why do cluster size, charge state, and ligands affect the course of metal‐mediated gas‐phase activation of methane?

H Schwarz - Israel Journal of Chemistry, 2014 - Wiley Online Library
Recent progress in the gas‐phase activation of methane is discussed. We demonstrate that
cluster size, charge state, and ligands crucially affect both the reactivity and selectivity of …

Chemie mit Methan: Studieren geht über Probieren!

H Schwarz - Angewandte Chemie, 2011 - Wiley Online Library
Konzeptionelle Überlegungen zu und mechanistische Aspekte von vier scheinbar einfachen
chemischen Umsetzungen, die in der Chemie von Methan von Bedeutung sind, werden in …

HCN Synthesis from Methane and Ammonia:  Mechanisms of Pt+-Mediated C−N Coupling

M Diefenbach, M Brönstrup, M Aschi… - Journal of the …, 1999 - ACS Publications
The Pt+-mediated coupling of methane and ammonia has been studied both experimentally
and computationally. This system serves as a model for the Degussa process for the …

Oxidation studies of dipositive actinide ions, An2+ (An= Th, U, Np, Pu, Am) in the gas phase: Synthesis and characterization of the isolated uranyl, neptunyl, and …

JK Gibson, RG Haire, M Santos, J Marçalo… - The Journal of …, 2005 - ACS Publications
Reactions of atomic and ligated dipositive actinide ions, An2+, AnO2+, AnOH2+, and
AnO22+ (An= Th, U, Np, Pu, Am) were systematically studied by Fourier transform ion …

Gas-phase oxidation reactions of neptunium and plutonium ions investigated via Fourier transform ion cyclotron resonance mass spectrometry

M Santos, J Marçalo, A Pires de Matos… - The Journal of …, 2002 - ACS Publications
The first gas-phase ion chemistry studies of the transuranium actinides Np and Pu by Fourier
Transform Ion Cyclotron Resonance Mass Spectrometry (FTICR-MS) have been performed …

Radionuclide analysis using collision–reaction cell ICP-MS technology: a review

S Diez-Fernández, H Isnard, A Nonell… - Journal of Analytical …, 2020 - pubs.rsc.org
The analysis of radionuclides (RN) is of major concern in different fields like the
environment, geosciences, the nuclear industry, and medical research. Inductively coupled …

Reactions of U+ with H2, D2, and HD Studied by Guided Ion Beam Tandem Mass Spectrometry and Theory

WJ Zhang, M Demireva, JS Kim… - The Journal of …, 2021 - ACS Publications
The kinetic energy-dependent reactions of the atomic actinide uranium cation (U+) with H2,
D2, and HD were examined by guided ion beam tandem mass spectrometry. An average 0 …

[HTML][HTML] Bond energies of ThO+ and ThC+: A guided ion beam and quantum chemical investigation of the reactions of thorium cation with O2 and CO

RM Cox, M Citir, PB Armentrout, SR Battey… - The Journal of …, 2016 - pubs.aip.org
Kinetic energy dependent reactions of Th+ with O 2 and CO are studied using a guided ion
beam tandem mass spectrometer. The formation of ThO+ in the reaction of Th+ with O 2 is …